Interfacial effects on the dynamics of cooperatively rearranging regions

C. Streck, X. Yan, R. Richert

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

The glass-forming liquid 2-methyltetrahydrofuran is particularly well described by the theory of Adam and Gibbs as regards the coupling between molecular dynamics and configurational entropy near the glass transition temperature at Tg = 91 K. Therefore, the underlying physical picture of cooperatively rearranging regions captures the temperature dependence of orientational dynamics for the bulk liquid on the basis of the configurational entropy. We demonstrate that geometrical confinement of such a liquid to nanopores gives rise to a dynamical coupling of the liquid to the rigid pore wall resulting in a non-ergodic regime for long time, whereas the short time dynamics remain unaffected.

Original languageEnglish (US)
Pages (from-to)1735-1737
Number of pages3
JournalBerichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
Volume101
Issue number11
DOIs
StatePublished - 1997
Externally publishedYes

Keywords

  • Dielectrics
  • Glasses
  • Interfaces
  • Molecular Interactions
  • Salvation Dynamics

ASJC Scopus subject areas

  • Chemical Engineering(all)

Fingerprint

Dive into the research topics of 'Interfacial effects on the dynamics of cooperatively rearranging regions'. Together they form a unique fingerprint.

Cite this