Integrated X-ray L absorption spectra. Counting holes in Ni complexes

Hongxin Wang, Pinghua Ge, C. G. Riordan, S. Brooker, C. G. Woomer, T. Collins, C. A. Melendres, Oliver Graudejus, N. Bartlett, S. P. Cramer

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

Despite the fact that chemists frequently draw electron density distributions, there are few good methods for measuring this quantity, which has contributed to many longstanding controversies in chemistry. In this paper, we report the first application of element specific L absorption spectra and the "white light" sum rule to a series of nickel complexes, with wide oxidation state range from NiI to NiIV. Nickel L edge X-ray absorption spectroscopy is turning out to be an excellent quantitative probe of 3d-vacancies.

Original languageEnglish (US)
Pages (from-to)8343-8346
Number of pages4
JournalJournal of Physical Chemistry B
Volume102
Issue number42
StatePublished - Oct 15 1998
Externally publishedYes

Fingerprint

Nickel
Absorption spectra
counting
X-Ray Absorption Spectroscopy
X-Rays
nickel
absorption spectra
X rays
Electronic density of states
X ray absorption spectroscopy
sum rules
Vacancies
density distribution
absorption spectroscopy
x rays
Electrons
chemistry
Light
Oxidation
oxidation

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Wang, H., Ge, P., Riordan, C. G., Brooker, S., Woomer, C. G., Collins, T., ... Cramer, S. P. (1998). Integrated X-ray L absorption spectra. Counting holes in Ni complexes. Journal of Physical Chemistry B, 102(42), 8343-8346.

Integrated X-ray L absorption spectra. Counting holes in Ni complexes. / Wang, Hongxin; Ge, Pinghua; Riordan, C. G.; Brooker, S.; Woomer, C. G.; Collins, T.; Melendres, C. A.; Graudejus, Oliver; Bartlett, N.; Cramer, S. P.

In: Journal of Physical Chemistry B, Vol. 102, No. 42, 15.10.1998, p. 8343-8346.

Research output: Contribution to journalArticle

Wang, H, Ge, P, Riordan, CG, Brooker, S, Woomer, CG, Collins, T, Melendres, CA, Graudejus, O, Bartlett, N & Cramer, SP 1998, 'Integrated X-ray L absorption spectra. Counting holes in Ni complexes', Journal of Physical Chemistry B, vol. 102, no. 42, pp. 8343-8346.
Wang H, Ge P, Riordan CG, Brooker S, Woomer CG, Collins T et al. Integrated X-ray L absorption spectra. Counting holes in Ni complexes. Journal of Physical Chemistry B. 1998 Oct 15;102(42):8343-8346.
Wang, Hongxin ; Ge, Pinghua ; Riordan, C. G. ; Brooker, S. ; Woomer, C. G. ; Collins, T. ; Melendres, C. A. ; Graudejus, Oliver ; Bartlett, N. ; Cramer, S. P. / Integrated X-ray L absorption spectra. Counting holes in Ni complexes. In: Journal of Physical Chemistry B. 1998 ; Vol. 102, No. 42. pp. 8343-8346.
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