Integrated X-ray L absorption spectra. Counting holes in Ni complexes

Hongxin Wang; Pinghua Ge; C. G. Riordan; S. Brooker; C. G. Woomer; T. Collins; C. A. Melendres; O. Graudejus; N. Bartlett; S. P. Cramer

doi:10.1021/jp9821026

Integrated X-ray L absorption spectra. Counting holes in Ni complexes

Hongxin Wang, Pinghua Ge, C. G. Riordan, S. Brooker, C. G. Woomer, T. Collins, C. A. Melendres, O. Graudejus, N. Bartlett, S. P. Cramer

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

Despite the fact that chemists frequently draw electron density distributions, there are few good methods for measuring this quantity, which has contributed to many longstanding controversies in chemistry. In this paper, we report the first application of element specific L absorption spectra and the "white light" sum rule to a series of nickel complexes, with wide oxidation state range from Ni^I to Ni^IV. Nickel L edge X-ray absorption spectroscopy is turning out to be an excellent quantitative probe of 3d-vacancies.

Original language	English (US)
Pages (from-to)	8343-8346
Number of pages	4
Journal	Journal of Physical Chemistry B
Volume	102
Issue number	42
DOIs	https://doi.org/10.1021/jp9821026
State	Published - Oct 15 1998
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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abstract = "Despite the fact that chemists frequently draw electron density distributions, there are few good methods for measuring this quantity, which has contributed to many longstanding controversies in chemistry. In this paper, we report the first application of element specific L absorption spectra and the {"}white light{"} sum rule to a series of nickel complexes, with wide oxidation state range from NiI to NiIV. Nickel L edge X-ray absorption spectroscopy is turning out to be an excellent quantitative probe of 3d-vacancies.",

author = "Hongxin Wang and Pinghua Ge and Riordan, {C. G.} and S. Brooker and Woomer, {C. G.} and T. Collins and Melendres, {C. A.} and O. Graudejus and N. Bartlett and Cramer, {S. P.}",

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T1 - Integrated X-ray L absorption spectra. Counting holes in Ni complexes

AU - Wang, Hongxin

AU - Ge, Pinghua

AU - Riordan, C. G.

AU - Brooker, S.

AU - Woomer, C. G.

AU - Collins, T.

AU - Melendres, C. A.

AU - Graudejus, O.

AU - Bartlett, N.

AU - Cramer, S. P.

PY - 1998/10/15

Y1 - 1998/10/15

N2 - Despite the fact that chemists frequently draw electron density distributions, there are few good methods for measuring this quantity, which has contributed to many longstanding controversies in chemistry. In this paper, we report the first application of element specific L absorption spectra and the "white light" sum rule to a series of nickel complexes, with wide oxidation state range from NiI to NiIV. Nickel L edge X-ray absorption spectroscopy is turning out to be an excellent quantitative probe of 3d-vacancies.

AB - Despite the fact that chemists frequently draw electron density distributions, there are few good methods for measuring this quantity, which has contributed to many longstanding controversies in chemistry. In this paper, we report the first application of element specific L absorption spectra and the "white light" sum rule to a series of nickel complexes, with wide oxidation state range from NiI to NiIV. Nickel L edge X-ray absorption spectroscopy is turning out to be an excellent quantitative probe of 3d-vacancies.

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JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 42

ER -

Integrated X-ray L absorption spectra. Counting holes in Ni complexes

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