Abstract
The previously unknown experimental HfO2–Ta2O5-temperature phase diagram has been elucidated up to 3000°C using a quadrupole lamp furnace and conical nozzle levitator system equipped with a CO2 laser, in conjunction with synchrotron X-ray diffraction. These in-situ techniques allowed the determination of the following: (a) liquidus, solidus, and invariant transformation temperatures as a function of composition from thermal arrest experiments, (b) determination of equilibrium phases through testing of reversibility via in-situ X-ray diffraction, and (c) molar volume measurements as a function of temperature for equilibrium phases. From these, an experimental HfO2–Ta2O5-temperature phase diagram has been constructed which is consistent with the Gibbs Phase Rule.
Original language | English (US) |
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Pages (from-to) | 4848-4861 |
Number of pages | 14 |
Journal | Journal of the American Ceramic Society |
Volume | 102 |
Issue number | 8 |
DOIs | |
State | Published - Aug 2019 |
Externally published | Yes |
ASJC Scopus subject areas
- Ceramics and Composites
- Materials Chemistry