TY - JOUR
T1 - Hydrophilically engineered polyacrylonitrile nanofiber aerogel as a soft template for large mass loading of mesoporous poly(3,4-ethylenedioxythiophene) network on a bare metal wire for high-rate wire-shaped supercapacitors
AU - Lai, Haoran
AU - Li, Wenyue
AU - Zhou, Yang
AU - He, Tianyu
AU - Xu, Ling
AU - Tian, Siyu
AU - Wang, Xiaoming
AU - Fan, Zhaoyang
AU - Lei, Zhongli
AU - Jiao, Huan
N1 - Funding Information:
The Project was sponsored by the National Natural Science Foundation of China ( 51373093 , 51272151 and 51672167 ), the Natural Science Foundation of Shaanxi Province ( 2014JZ002 , 2015JQ2041 ), Fundamental Research Funds for the Central Universities ( GK201701011 and 2016CBZ004 ), and Science and Technology program of Xi'an ( 2017071CG/RC034(SXSF004) ).
PY - 2019/11/30
Y1 - 2019/11/30
N2 - Wire-shaped solid-state supercapacitors (WSSCs) receive ever-growing interest for developing electronic textile. How to achieve a high active mass loading with a suitable mesoporous structure and strong adhesion on a bare metal wire are a severe challenge faced by the development of practical WSSCs, which must meet requirements such as high energy and power densities, fast rate capability, as well as flexibility and stability. Here, a new strategy to synthesize the wire-shaped electrode with excellent electrochemical and mechanical performances is reported using a soft aerogel template in a facile dip coating process. Hydrophilically engineered polyacrylonitrile nanofibers by adding glycerol were electrospun on a Ti metal wire to form the sacrificial aerogel template with a huge void volume, in which poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) solution was dip coated to achieve a large mass loading. The capillary effect in the subsequent natural drying process, slow dissolution of the template in a solvent, and PSS etching, together lead to a mesoporous PEDOT thick coating network formed on the metal wire with a high conductivity, strong mechanical strength and intimate interface adhesion. The resulted WSSCs based on Ti/PEDOT electrodes, exhibited a fairly wide potential window, large specific capacitance, ultrahigh rate capability and energy/power densities.
AB - Wire-shaped solid-state supercapacitors (WSSCs) receive ever-growing interest for developing electronic textile. How to achieve a high active mass loading with a suitable mesoporous structure and strong adhesion on a bare metal wire are a severe challenge faced by the development of practical WSSCs, which must meet requirements such as high energy and power densities, fast rate capability, as well as flexibility and stability. Here, a new strategy to synthesize the wire-shaped electrode with excellent electrochemical and mechanical performances is reported using a soft aerogel template in a facile dip coating process. Hydrophilically engineered polyacrylonitrile nanofibers by adding glycerol were electrospun on a Ti metal wire to form the sacrificial aerogel template with a huge void volume, in which poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) solution was dip coated to achieve a large mass loading. The capillary effect in the subsequent natural drying process, slow dissolution of the template in a solvent, and PSS etching, together lead to a mesoporous PEDOT thick coating network formed on the metal wire with a high conductivity, strong mechanical strength and intimate interface adhesion. The resulted WSSCs based on Ti/PEDOT electrodes, exhibited a fairly wide potential window, large specific capacitance, ultrahigh rate capability and energy/power densities.
KW - Aerogel
KW - Flexible supercapacitors
KW - Hydrophilicity
KW - Wearable energy storage
KW - Wire-shaped electrode
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U2 - 10.1016/j.jpowsour.2019.227212
DO - 10.1016/j.jpowsour.2019.227212
M3 - Article
AN - SCOPUS:85072624713
VL - 441
JO - Journal of Power Sources
JF - Journal of Power Sources
SN - 0378-7753
M1 - 227212
ER -