Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization

Jing Zhang; Milan Gembicky; Marc Messerschmidt; Philip Coppens

doi:10.1039/b700073a

Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization

Jing Zhang, Milan Gembicky, Marc Messerschmidt, Philip Coppens

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Intermolecular H-bonding between C=O (ketone) and HO (4′- hydroxyphenyl) quenches photodecarbonylation of 2,2,4,4-tetramethyl-1,3- di(4′-hydroxyphenyl)acetone 1 in the crystalline solid state, its reactivity is recovered by co-crystallization with the small organic molecule 4,4′-bicyclohexanone.

Original language	English (US)
Pages (from-to)	2399-2401
Number of pages	3
Journal	Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/b700073a
State	Published - Jan 1 2007
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization",

abstract = "Intermolecular H-bonding between C=O (ketone) and HO (4′- hydroxyphenyl) quenches photodecarbonylation of 2,2,4,4-tetramethyl-1,3- di(4′-hydroxyphenyl)acetone 1 in the crystalline solid state, its reactivity is recovered by co-crystallization with the small organic molecule 4,4′-bicyclohexanone.",

author = "Jing Zhang and Milan Gembicky and Marc Messerschmidt and Philip Coppens",

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doi = "10.1039/b700073a",

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AU - Zhang, Jing

AU - Gembicky, Milan

AU - Messerschmidt, Marc

AU - Coppens, Philip

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Y1 - 2007/1/1

N2 - Intermolecular H-bonding between C=O (ketone) and HO (4′- hydroxyphenyl) quenches photodecarbonylation of 2,2,4,4-tetramethyl-1,3- di(4′-hydroxyphenyl)acetone 1 in the crystalline solid state, its reactivity is recovered by co-crystallization with the small organic molecule 4,4′-bicyclohexanone.

AB - Intermolecular H-bonding between C=O (ketone) and HO (4′- hydroxyphenyl) quenches photodecarbonylation of 2,2,4,4-tetramethyl-1,3- di(4′-hydroxyphenyl)acetone 1 in the crystalline solid state, its reactivity is recovered by co-crystallization with the small organic molecule 4,4′-bicyclohexanone.

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Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization

Abstract

ASJC Scopus subject areas

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