Hole transport in 1,1-bis(di-4-tolylaminophenyl)cyclohexane

P. M. Borsenberger, L. Pautmeier, R. Richert, H. Bässler

Research output: Contribution to journalArticlepeer-review

190 Scopus citations

Abstract

Hole mobilities have been measured in vapor deposited films of 1,1-bis (di-4-tolylaminophenyl)cyclohexane over an extended range of fields and temperatures. At 295 K, the mobility is approximately 10-2 cm 2/V s, the highest value for a disordered molecular solid reported thus far. Monte Carlo simulations of random walk in a geometrically and energetically disordered medium demonstrate that the time dependence of the photocurrent and the field and temperature dependencies of the mobility can be described quantitatively in terms of the inherent disorder and its effect on charge transport. No polaronic or trapping phenomena need to be invoked to reproduce even subtle features of the experimental results.

Original languageEnglish (US)
Pages (from-to)8276-8281
Number of pages6
JournalThe Journal of chemical physics
Volume94
Issue number12
DOIs
StatePublished - Jan 1 1991
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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