Highly Efficient Alkylation Using Hydrophobic Sulfonic Acid-Functionalized Biochar as a Catalyst for Synthesis of High-Density Biofuels

Yao Zhong, Peixin Zhang, Xiaomin Zhu, Huan Li, Qiang Deng, Jun Wang, Zheling Zeng, Ji Jun Zou, Shuguang Deng

Research output: Contribution to journalArticle

2 Scopus citations

Abstract

Because H2O decreases the acidity of sulfonic acid-based catalysts and initiates catalytic side reactions, the catalytic activity and selectivity of these catalysts are often unsatisfactory in many reactions that generate H2O as a byproduct. Herein, for the first time, hydrophobic acid-functionalized biochar is prepared by a new route based on a two-step diazo grafting method using 4-aminobenzenesulfonic acid as the sulfonated agent and 4-tert-butylaniline as the hydrophobic agent. The acid density and hydrophobicity can be easily regulated by the amounts of benzenesulfonic acid and tert-butylbenzene groups, respectively. The resulting catalysts have a large specific surface area of 400-700 m2/g, high acid density of greater than 2.0 mmol/g, and strong hydrophobicity with an H2O contact angle of up to 136°. Compared with Amberlyst-15 and H2SO4-sulfonated biochar, the hydrophobic acidic biochar exhibits higher activity and selectivity in the alkylation of 4-ethylphenol with phenylmethanol and of 2-methylfuran with cyclic ketones (cyclopentanone and cyclohexanone) for the production of high-density biofuels. The successful preparation of the hydrophobic acidic biochar not only results in an efficient catalyst for reaction systems in which H2O has a deleterious effect but also paves a way for the functional modification of carbonaceous materials.

Original languageEnglish (US)
Pages (from-to)14973-14981
Number of pages9
JournalACS Sustainable Chemistry and Engineering
Volume7
Issue number17
DOIs
StatePublished - Sep 3 2019

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Keywords

  • alkylation
  • diazo method
  • high-density biofuel
  • hydrophobicity
  • sulfonic acid-functionalized biochar

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment

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