TY - JOUR
T1 - Highly Crosslinked Conductive Polymer Nanofibrous Films for High-Rate Solid-State Supercapacitors and Electromagnetic Interference Shielding
AU - Lai, Haoran
AU - Bai, Congrui
AU - Wang, Yaqin
AU - Fan, Zhaoyang
AU - Yuan, Ye
AU - Jiao, Huan
N1 - Funding Information:
This work was supported by the grant from the National Natural Science Foundation of China (51272151 and 51672167), the Natural Science Foundation of Shaanxi Province (2014JZ002, 2015JQ2041), Fundamental Research Funds for the Central Universities (GK201701011 and 2016CBZ004), and Science and Technology program of Xi'an (2017071CG/ RC034(SXSF004)).
Publisher Copyright:
© 2022 Wiley-VCH GmbH
PY - 2022/3/22
Y1 - 2022/3/22
N2 - With their low cost and unique physicochemical properties, conductive polymer- based film electrodes drew much attention in flexible electronic devices. However, their poor intrinsic conductivities limit their applications in high-rate supercapacitors or high electromagnetic interference (EMI) shielding performance. It is meaningful to deal with the issue through the rational design of the film nanostructure. Herein, using specially treated PEDOT:PSS coated polyacrylonitrile (PAN) nanofibrous films (PPNFs) as a current collector, polyaniline (PANI) or polypyrrole (PPy) based highly crosslinked conductive nanofibrous films (HCC-NFs), named as PANI@PPNF and PPy@PPNF, are fabricated. The PANI@PPNF electrodes exhibit a specific capacitance of 156 mF cm–2 at a current density of 1 mA cm–2. Meanwhile, 41% capacity (64 mF cm–2) remained even at 20 mA cm–2. The remarkable rate performance of PANI@PPNFs demonstrates the HCC-NF structure brings a high-rate character for pseudocapacitive material. Furthermore, the solid-state supercapacitor shows long-term cycle stability at a high scan rate of 1 V s–1 for 5 000 cycles and over 75% of the specific capacitance is retained, suggesting excellent cycle stability of PANI@PPNF. Besides, PANI or PPy based HCC-NFs show high performance in EMI shielding. This conductive polymer-based HCC-NF structure offers a promising platform for designing multi-functional flexible electronic devices.
AB - With their low cost and unique physicochemical properties, conductive polymer- based film electrodes drew much attention in flexible electronic devices. However, their poor intrinsic conductivities limit their applications in high-rate supercapacitors or high electromagnetic interference (EMI) shielding performance. It is meaningful to deal with the issue through the rational design of the film nanostructure. Herein, using specially treated PEDOT:PSS coated polyacrylonitrile (PAN) nanofibrous films (PPNFs) as a current collector, polyaniline (PANI) or polypyrrole (PPy) based highly crosslinked conductive nanofibrous films (HCC-NFs), named as PANI@PPNF and PPy@PPNF, are fabricated. The PANI@PPNF electrodes exhibit a specific capacitance of 156 mF cm–2 at a current density of 1 mA cm–2. Meanwhile, 41% capacity (64 mF cm–2) remained even at 20 mA cm–2. The remarkable rate performance of PANI@PPNFs demonstrates the HCC-NF structure brings a high-rate character for pseudocapacitive material. Furthermore, the solid-state supercapacitor shows long-term cycle stability at a high scan rate of 1 V s–1 for 5 000 cycles and over 75% of the specific capacitance is retained, suggesting excellent cycle stability of PANI@PPNF. Besides, PANI or PPy based HCC-NFs show high performance in EMI shielding. This conductive polymer-based HCC-NF structure offers a promising platform for designing multi-functional flexible electronic devices.
KW - conductive polymer
KW - crosslink
KW - electromagnetic interference shielding
KW - high-rate supercapacitor
UR - http://www.scopus.com/inward/record.url?scp=85123986837&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85123986837&partnerID=8YFLogxK
U2 - 10.1002/admi.202102115
DO - 10.1002/admi.202102115
M3 - Article
AN - SCOPUS:85123986837
SN - 2196-7350
VL - 9
JO - Advanced Materials Interfaces
JF - Advanced Materials Interfaces
IS - 9
M1 - 2102115
ER -