High temperature sorption of carbon dioxide on perovskite-type metal oxides

Jerry Lin, Qing Yang, Junichi Ida

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Understanding chemical sorption of carbon dioxide on perovskite-type oxides is important to applications of these metal oxides as sorbents, membranes and catalysts in several separation and reaction processes. The present study reports on equilibrium and kinetic data for chemical sorption of carbon dioxide on Sr0.5Ca0.5Co0.5Fe0.5O3. At temperatures below 750 °C the sorption process can be described by the classical theory for chemical sorption by means of the gas-solid reaction. The equilibrium carbon dioxide sorption capacity is independent but the sorption kinetic rate is a strong function of temperature and carbon dioxide pressure. Above 750 °C, the equilibrium carbon dioxide sorption capacity decreases with increasing temperature and decreasing carbon dioxide pressure. It is suggested that at the high temperatures the reaction products include solid solution of SrCO3/SrO and CaCO3/CaO, respectively. The equilibrium carbon dioxide sorption capacity depends on the conversion of the carbonate to the corresponding metal oxide determined by temperature and carbon dioxide partial pressure.

Original languageEnglish (US)
Pages (from-to)276-280
Number of pages5
JournalJournal of the Taiwan Institute of Chemical Engineers
Volume40
Issue number3
DOIs
StatePublished - May 2009

Fingerprint

Carbon Dioxide
Perovskite
Oxides
Sorption
Carbon dioxide
Metals
Temperature
Kinetics
perovskite
Carbonates
Sorbents
Reaction products
Partial pressure
Solid solutions
Gases
Membranes
Catalysts

Keywords

  • Carbon dioxide
  • Chemical sorption
  • Perovskite-type oxides
  • Reaction equilibrium

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

High temperature sorption of carbon dioxide on perovskite-type metal oxides. / Lin, Jerry; Yang, Qing; Ida, Junichi.

In: Journal of the Taiwan Institute of Chemical Engineers, Vol. 40, No. 3, 05.2009, p. 276-280.

Research output: Contribution to journalArticle

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AB - Understanding chemical sorption of carbon dioxide on perovskite-type oxides is important to applications of these metal oxides as sorbents, membranes and catalysts in several separation and reaction processes. The present study reports on equilibrium and kinetic data for chemical sorption of carbon dioxide on Sr0.5Ca0.5Co0.5Fe0.5O3. At temperatures below 750 °C the sorption process can be described by the classical theory for chemical sorption by means of the gas-solid reaction. The equilibrium carbon dioxide sorption capacity is independent but the sorption kinetic rate is a strong function of temperature and carbon dioxide pressure. Above 750 °C, the equilibrium carbon dioxide sorption capacity decreases with increasing temperature and decreasing carbon dioxide pressure. It is suggested that at the high temperatures the reaction products include solid solution of SrCO3/SrO and CaCO3/CaO, respectively. The equilibrium carbon dioxide sorption capacity depends on the conversion of the carbonate to the corresponding metal oxide determined by temperature and carbon dioxide partial pressure.

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