High temperature heat content and diffuse transition of lead fluoride

C. E. Derrington; A. Navrotsky; M. O'Keeffe

doi:10.1016/0038-1098(76)91398-3

High temperature heat content and diffuse transition of lead fluoride

C. E. Derrington, A. Navrotsky, M. O'Keeffe

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

The high temperature heat content of crystalline PbF₂ increases rapidly between 625 and 750 K, with an antropy incre ase of 16.5 JK^-1 mol^-1. The region of rapid heat content increase correlates with a large increase in ionic conductivity and is associated with fluoride ion disorder.

Original language	English (US)
Pages (from-to)	47-49
Number of pages	3
Journal	Solid State Communications
Volume	18
Issue number	1
DOIs	https://doi.org/10.1016/0038-1098(76)91398-3
State	Published - 1976

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Materials Chemistry

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10.1016/0038-1098(76)91398-3

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title = "High temperature heat content and diffuse transition of lead fluoride",

abstract = "The high temperature heat content of crystalline PbF2 increases rapidly between 625 and 750 K, with an antropy incre ase of 16.5 JK-1 mol-1. The region of rapid heat content increase correlates with a large increase in ionic conductivity and is associated with fluoride ion disorder.",

author = "Derrington, {C. E.} and A. Navrotsky and M. O'Keeffe",

note = "Funding Information: Acknowledgements — This work was supported by grants from the National Science Foundation to M. O{\textquoteright}Keeffe and A. Navrotsky. We acknowledge the assistance of John Sharples and Lane Briley.",

year = "1976",

doi = "10.1016/0038-1098(76)91398-3",

language = "English (US)",

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pages = "47--49",

journal = "Solid State Communications",

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T1 - High temperature heat content and diffuse transition of lead fluoride

AU - Derrington, C. E.

AU - Navrotsky, A.

AU - O'Keeffe, M.

N1 - Funding Information: Acknowledgements — This work was supported by grants from the National Science Foundation to M. O’Keeffe and A. Navrotsky. We acknowledge the assistance of John Sharples and Lane Briley.

PY - 1976

Y1 - 1976

N2 - The high temperature heat content of crystalline PbF2 increases rapidly between 625 and 750 K, with an antropy incre ase of 16.5 JK-1 mol-1. The region of rapid heat content increase correlates with a large increase in ionic conductivity and is associated with fluoride ion disorder.

AB - The high temperature heat content of crystalline PbF2 increases rapidly between 625 and 750 K, with an antropy incre ase of 16.5 JK-1 mol-1. The region of rapid heat content increase correlates with a large increase in ionic conductivity and is associated with fluoride ion disorder.

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DO - 10.1016/0038-1098(76)91398-3

M3 - Article

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JO - Solid State Communications

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IS - 1

ER -

High temperature heat content and diffuse transition of lead fluoride

Abstract

ASJC Scopus subject areas

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