High-resolution study of 13C16O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL: Revised term values

Lisseth Gavilan; Jean Louis Lemaire; Michèle Eidelsberg; S. R. Federman; Glenn Stark; Alan N. Heays; Jean Hugues Fillion; James R. Lyons; Nelson De Oliveira

doi:10.1021/jp312338z

High-resolution study of ¹³C¹⁶O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL: Revised term values

Lisseth Gavilan, Jean Louis Lemaire, Michèle Eidelsberg, S. R. Federman, Glenn Stark, Alan N. Heays, Jean Hugues Fillion, James R. Lyons, Nelson De Oliveira

Earth and Space Exploration, School of (SESE)

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

We present high-resolution absorption spectral measurements of the A ¹Π-X¹Σ⁺ band system of ¹³C¹⁶O. These were recorded with the VUV Fourier transform spectrometer (VUV-FTS) installed on the DESIRS beamline at the SOLEIL synchrotron. This work includes revised term values that extend to higher J' values than previous measurements for most v' levels and lower J' values for v' = 0. We confirm previously observed perturbations of the rotational levels in greater detail and present evidence for new perturbations. The accuracy in the wavelength determination and term values is on average within 0.01 cm ^-1, improving upon previous measurements.

Original language	English (US)
Pages (from-to)	9644-9652
Number of pages	9
Journal	Journal of Physical Chemistry A
Volume	117
Issue number	39
DOIs	https://doi.org/10.1021/jp312338z
State	Published - Oct 3 2013

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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10.1021/jp312338z

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title = "High-resolution study of 13C16O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL: Revised term values",

abstract = "We present high-resolution absorption spectral measurements of the A 1Π-X1Σ+ band system of 13C16O. These were recorded with the VUV Fourier transform spectrometer (VUV-FTS) installed on the DESIRS beamline at the SOLEIL synchrotron. This work includes revised term values that extend to higher J' values than previous measurements for most v' levels and lower J' values for v' = 0. We confirm previously observed perturbations of the rotational levels in greater detail and present evidence for new perturbations. The accuracy in the wavelength determination and term values is on average within 0.01 cm -1, improving upon previous measurements.",

author = "Lisseth Gavilan and Lemaire, {Jean Louis} and Mich{\`e}le Eidelsberg and Federman, {S. R.} and Glenn Stark and Heays, {Alan N.} and Fillion, {Jean Hugues} and Lyons, {James R.} and {De Oliveira}, Nelson",

year = "2013",

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doi = "10.1021/jp312338z",

language = "English (US)",

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journal = "Journal of Physical Chemistry A",

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TY - JOUR

T1 - High-resolution study of 13C16O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL

T2 - Revised term values

AU - Gavilan, Lisseth

AU - Lemaire, Jean Louis

AU - Eidelsberg, Michèle

AU - Federman, S. R.

AU - Stark, Glenn

AU - Heays, Alan N.

AU - Fillion, Jean Hugues

AU - Lyons, James R.

AU - De Oliveira, Nelson

PY - 2013/10/3

Y1 - 2013/10/3

N2 - We present high-resolution absorption spectral measurements of the A 1Π-X1Σ+ band system of 13C16O. These were recorded with the VUV Fourier transform spectrometer (VUV-FTS) installed on the DESIRS beamline at the SOLEIL synchrotron. This work includes revised term values that extend to higher J' values than previous measurements for most v' levels and lower J' values for v' = 0. We confirm previously observed perturbations of the rotational levels in greater detail and present evidence for new perturbations. The accuracy in the wavelength determination and term values is on average within 0.01 cm -1, improving upon previous measurements.

AB - We present high-resolution absorption spectral measurements of the A 1Π-X1Σ+ band system of 13C16O. These were recorded with the VUV Fourier transform spectrometer (VUV-FTS) installed on the DESIRS beamline at the SOLEIL synchrotron. This work includes revised term values that extend to higher J' values than previous measurements for most v' levels and lower J' values for v' = 0. We confirm previously observed perturbations of the rotational levels in greater detail and present evidence for new perturbations. The accuracy in the wavelength determination and term values is on average within 0.01 cm -1, improving upon previous measurements.

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IS - 39

ER -

High-resolution study of ¹³C¹⁶O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL: Revised term values

Abstract

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