High-resolution study of 13C16O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL

Revised term values

Lisseth Gavilan, Jean Louis Lemaire, Michèle Eidelsberg, S. R. Federman, Glenn Stark, Alan N. Heays, Jean Hugues Fillion, James Lyons, Nelson De Oliveira

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

We present high-resolution absorption spectral measurements of the A 1Π-X1Σ+ band system of 13C16O. These were recorded with the VUV Fourier transform spectrometer (VUV-FTS) installed on the DESIRS beamline at the SOLEIL synchrotron. This work includes revised term values that extend to higher J' values than previous measurements for most v' levels and lower J' values for v' = 0. We confirm previously observed perturbations of the rotational levels in greater detail and present evidence for new perturbations. The accuracy in the wavelength determination and term values is on average within 0.01 cm -1, improving upon previous measurements.

Original languageEnglish (US)
Pages (from-to)9644-9652
Number of pages9
JournalJournal of Physical Chemistry A
Volume117
Issue number39
DOIs
StatePublished - Oct 3 2013
Externally publishedYes

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Spectrometers
Fourier transforms
spectrometers
high resolution
Synchrotrons
perturbation
Wavelength
synchrotrons
absorption spectra
wavelengths

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Gavilan, L., Lemaire, J. L., Eidelsberg, M., Federman, S. R., Stark, G., Heays, A. N., ... De Oliveira, N. (2013). High-resolution study of 13C16O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL: Revised term values. Journal of Physical Chemistry A, 117(39), 9644-9652. https://doi.org/10.1021/jp312338z

High-resolution study of 13C16O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL : Revised term values. / Gavilan, Lisseth; Lemaire, Jean Louis; Eidelsberg, Michèle; Federman, S. R.; Stark, Glenn; Heays, Alan N.; Fillion, Jean Hugues; Lyons, James; De Oliveira, Nelson.

In: Journal of Physical Chemistry A, Vol. 117, No. 39, 03.10.2013, p. 9644-9652.

Research output: Contribution to journalArticle

Gavilan, L, Lemaire, JL, Eidelsberg, M, Federman, SR, Stark, G, Heays, AN, Fillion, JH, Lyons, J & De Oliveira, N 2013, 'High-resolution study of 13C16O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL: Revised term values', Journal of Physical Chemistry A, vol. 117, no. 39, pp. 9644-9652. https://doi.org/10.1021/jp312338z
Gavilan, Lisseth ; Lemaire, Jean Louis ; Eidelsberg, Michèle ; Federman, S. R. ; Stark, Glenn ; Heays, Alan N. ; Fillion, Jean Hugues ; Lyons, James ; De Oliveira, Nelson. / High-resolution study of 13C16O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL : Revised term values. In: Journal of Physical Chemistry A. 2013 ; Vol. 117, No. 39. pp. 9644-9652.
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