High and selective CO2 adsorption by a phthalocyanine nanoporous polymer

Venkata S.Pavan K. Neti, Jun Wang, Shuguang Deng, Luis Echegoyen

Research output: Contribution to journalArticlepeer-review

40 Scopus citations

Abstract

A rigid macrocyclic phthalocyanine-based porous polymer, CPP, was synthesized by a one pot "click" reaction between tetraazido-phthalocyanine and bisamine diethynylbenzene. This CPP is the first example of a phthalocyanine porous polymer used for CO2 adsorption and it shows very high CO2 adsorption (15.7 wt% at 273 K/1 bar) and high selectivity for CO2/N2 (94) and for CO2/CH4 (12.8) at 273 K/1 bar. The CPP exhibited a Brunauer-Emmett-Teller (BET) surface area of 579 m2 g-1 and high thermal stability up to 500 °C, thus showing good potential for CO2 capture.

Original languageEnglish (US)
Pages (from-to)10284-10288
Number of pages5
JournalJournal of Materials Chemistry A
Volume3
Issue number19
DOIs
StatePublished - May 21 2015
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

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