High and selective CO2 adsorption by a phthalocyanine nanoporous polymer

Venkata S Pavan K Neti, Jun Wang, Shuguang Deng, Luis Echegoyen

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

A rigid macrocyclic phthalocyanine-based porous polymer, CPP, was synthesized by a one pot "click" reaction between tetraazido-phthalocyanine and bisamine diethynylbenzene. This CPP is the first example of a phthalocyanine porous polymer used for CO2 adsorption and it shows very high CO2 adsorption (15.7 wt% at 273 K/1 bar) and high selectivity for CO2/N2 (94) and for CO2/CH4 (12.8) at 273 K/1 bar. The CPP exhibited a Brunauer-Emmett-Teller (BET) surface area of 579 m2 g-1 and high thermal stability up to 500 °C, thus showing good potential for CO2 capture.

Original languageEnglish (US)
Pages (from-to)10284-10288
Number of pages5
JournalJournal of Materials Chemistry A
Volume3
Issue number19
DOIs
StatePublished - May 21 2015
Externally publishedYes

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Polymers
Adsorption
Thermodynamic stability
phthalocyanine
3-(2-carboxypiperazin-4-yl)propyl-1-phosphonic acid

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

High and selective CO2 adsorption by a phthalocyanine nanoporous polymer. / Neti, Venkata S Pavan K; Wang, Jun; Deng, Shuguang; Echegoyen, Luis.

In: Journal of Materials Chemistry A, Vol. 3, No. 19, 21.05.2015, p. 10284-10288.

Research output: Contribution to journalArticle

Neti, Venkata S Pavan K ; Wang, Jun ; Deng, Shuguang ; Echegoyen, Luis. / High and selective CO2 adsorption by a phthalocyanine nanoporous polymer. In: Journal of Materials Chemistry A. 2015 ; Vol. 3, No. 19. pp. 10284-10288.
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