Glass-forming composition regions and glass transition temperature in nonaqueous electrolyte solutions

E. J. Sare, Charles Angell

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

With an interest in assessing the suitability of various nonaqueous solutions for electrolyte studies in the viscous region of the liquid state, the glass-forming properties of solutions of calcium nitrate dissolved in various nonaqueous solvents have been determined and compared with the corresponding aqueous solution properties. Solutions in dimethyl formamide prove of particular interest. The composition dependence of the glass temperature is similar in all solvents at high salt contents. "Ideal" glass temperatures, estimated from thermodynamic data for the pure solvents, are compared with experimental or extrapolated values.

Original languageEnglish (US)
Pages (from-to)53-57
Number of pages5
JournalJournal of Solution Chemistry
Volume2
Issue number1
DOIs
StatePublished - Feb 1973
Externally publishedYes

Fingerprint

nonaqueous electrolytes
Transition Temperature
glass transition temperature
Electrolytes
Glass
glass
Chemical analysis
Temperature
nitrates
calcium
Dimethylformamide
Thermodynamics
electrolytes
aqueous solutions
salts
thermodynamics
temperature
Salts
liquids
Glass transition temperature

Keywords

  • glass transition temperature
  • Nonaqueous electrolytes
  • relaxation processes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Glass-forming composition regions and glass transition temperature in nonaqueous electrolyte solutions. / Sare, E. J.; Angell, Charles.

In: Journal of Solution Chemistry, Vol. 2, No. 1, 02.1973, p. 53-57.

Research output: Contribution to journalArticle

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