Generalized model for NOx and N2O emissions from soils

W. J. Parton, E. A. Holland, S. J. Del Grosso, M. D. Hartman, R. E. Martin, A. R. Mosier, D. S. Ojima, D. S. Schimel

Research output: Contribution to journalArticle

269 Citations (Scopus)

Abstract

We describe a submodel to simulate NOx and N2O emissions from soils and present comparisons of simulated NOx and N2O fluxes from the DAYCENT ecosystem model with observations from different soils. The N gas flux submodel assumes that nitrification and denitrification both contribute to N2O and NOx emissions but that NOx emissions are due mainly to nitrification. N2O emissions from nitrification are calculated as a function of modeled soil NH4+ concentration, water-filled pore space (WFPS), temperature, pH, and texture. N2O emissions from denitrification are a function of soil NO3- concentration, WFPS, heterotrophic respiration, and texture. NOx emissions are calculated by multiplying total N2O emissions by a NOx:N2O equation which is calculated as a function of soil parameters (bulk density, field capacity, and WFPS) that influence gas diffusivity. The NOx submodel also simulates NOx emission pulses initiated by rain events onto dry soils. The DAYCENT model was tested by comparing observed and simulated parameters in grassland soils across a range of soil textures and fertility levels. Simulated values of soil temperature, WFPS (during the non-winter months), and NOx gas flux agreed reasonably well with measured values (r2 = 0.79, 0.64, and 0.43, respectively). Winter season WFPS was poorly simulated (r2 = 0.27). Although the correlation between simulated and observed N2O flux was poor on a daily basis (r2=0.02), DAYCENT was able to reproduce soil textural and treatment differences and the observed seasonal patterns of gas flux emissions with r2 values of 0.26 and 0.27, for monthly and NOx flux rates, respectively.

Original languageEnglish (US)
Article number2001JD900101
Pages (from-to)17403-17419
Number of pages17
JournalJournal of Geophysical Research Atmospheres
Volume106
Issue numberD15
DOIs
StatePublished - Aug 16 2001
Externally publishedYes

Fingerprint

soils
Soils
pore space
soil
Fluxes
Nitrification
porosity
gases
nitrification
Gases
Water
textures
Textures
Denitrification
gas
denitrification
water
texture
space temperature
fertility

ASJC Scopus subject areas

  • Geophysics
  • Forestry
  • Oceanography
  • Aquatic Science
  • Ecology
  • Water Science and Technology
  • Soil Science
  • Geochemistry and Petrology
  • Earth-Surface Processes
  • Atmospheric Science
  • Earth and Planetary Sciences (miscellaneous)
  • Space and Planetary Science
  • Palaeontology

Cite this

Parton, W. J., Holland, E. A., Del Grosso, S. J., Hartman, M. D., Martin, R. E., Mosier, A. R., ... Schimel, D. S. (2001). Generalized model for NOx and N2O emissions from soils. Journal of Geophysical Research Atmospheres, 106(D15), 17403-17419. [2001JD900101]. https://doi.org/10.1029/2001JD900101

Generalized model for NOx and N2O emissions from soils. / Parton, W. J.; Holland, E. A.; Del Grosso, S. J.; Hartman, M. D.; Martin, R. E.; Mosier, A. R.; Ojima, D. S.; Schimel, D. S.

In: Journal of Geophysical Research Atmospheres, Vol. 106, No. D15, 2001JD900101, 16.08.2001, p. 17403-17419.

Research output: Contribution to journalArticle

Parton, WJ, Holland, EA, Del Grosso, SJ, Hartman, MD, Martin, RE, Mosier, AR, Ojima, DS & Schimel, DS 2001, 'Generalized model for NOx and N2O emissions from soils', Journal of Geophysical Research Atmospheres, vol. 106, no. D15, 2001JD900101, pp. 17403-17419. https://doi.org/10.1029/2001JD900101
Parton WJ, Holland EA, Del Grosso SJ, Hartman MD, Martin RE, Mosier AR et al. Generalized model for NOx and N2O emissions from soils. Journal of Geophysical Research Atmospheres. 2001 Aug 16;106(D15):17403-17419. 2001JD900101. https://doi.org/10.1029/2001JD900101
Parton, W. J. ; Holland, E. A. ; Del Grosso, S. J. ; Hartman, M. D. ; Martin, R. E. ; Mosier, A. R. ; Ojima, D. S. ; Schimel, D. S. / Generalized model for NOx and N2O emissions from soils. In: Journal of Geophysical Research Atmospheres. 2001 ; Vol. 106, No. D15. pp. 17403-17419.
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AU - Martin, R. E.

AU - Mosier, A. R.

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