Gas diffusion and microstructural properties of ordered mesoporous silica fibers

Hatem M. Alsyouri, Jerry Lin

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

Pore and surface diffusion of carbon dioxide (CO 2) and ethylene (C 2H 4) in the nanopores of ordered mesoporous silica fibers about 200 μm in length was measured by the transient gravimetric method. The experimentally determined pore diffusivity data, coupled with the porosity, pore size, and fiber length, are used to obtain the actual length of the nanopores in silica fibers. These measurements reveal a structure of the ordered nanopores whirling helically around the fiber axis with a spiral diameter of about 15 μm and a pitch value of 1.6 μm. At room temperature the surface diffusion contributes about 10% to the total diffusional flux for these two gases in the nanopores of the ordered mesoporous silica fibers. The surface diffusion coefficients for the ordered mesoporous silica fibers are about 1 order of magnitude larger than the nonordered mesoporous alumina or silica with similar pore size.

Original languageEnglish (US)
Pages (from-to)13623-13629
Number of pages7
JournalJournal of Physical Chemistry B
Volume109
Issue number28
DOIs
StatePublished - Jul 21 2005

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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