@article{3d66fc9f05bc4fb4bf3b5c68e7850a40,
title = "Functionality in metal-organic framework minerals: Proton conductivity, stability and potential for polymorphism",
abstract = "Rare metal-organic framework (MOF) minerals stepanovite and zhemchuzhnikovite can exhibit properties comparable to known oxalate MOF proton conductors, including high proton conductivity over a range of relative humidities at 25 °C, and retention of the framework structure upon thermal dehydration. They also have high thermodynamic stability, with a pronounced stabilizing effect of substituting aluminium for iron, illustrating a simple design to access stable, highly proton-conductive MOFs without using complex organic ligands.",
author = "Igor Huski{\'c} and Novendra Novendra and Lim, {Dae Woon} and Filip Topi{\'c} and Titi, {Hatem M.} and Pekov, {Igor V.} and Krivovichev, {Sergey V.} and Alexandra Navrotsky and Hiroshi Kitagawa and Tomislav Fri{\v s}{\v c}i{\'c}",
note = "Funding Information: This work was funded by NSERC Discovery Grant (RGPIN-2017-06467) and NSERC E. W. R. Steacie Memorial Fellowship (SMFSU 507347-17). Calorimetry at UC Davis was supported by the U.S. Department of Energy Office of Science, grant DESC0016573. D.-W. Lim, and H. Kitagawa acknowledge the support from the ACCEL program, Japan Science and Technology Agency (JST), JPMJAC1501. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2019.",
year = "2019",
doi = "10.1039/c8sc05088k",
language = "English (US)",
volume = "10",
pages = "4923--4929",
journal = "Chemical Science",
issn = "2041-6520",
publisher = "Royal Society of Chemistry",
number = "18",
}