TY - GEN
T1 - From slags to molten salts to ionic liquids
T2 - 17th International Symposium on Molten Salts and Ionic Liquids - 218th ECS Meeting
AU - Angell, Charles
PY - 2010
Y1 - 2010
N2 - In the 1950's the literature on liquid silicates was mostly concerned with their function as scavengers for unwanted components in the metals extraction process. The slags were described as collections of oxide molecules. Then John Bockris, at Imperial College of Science, London, entered the scene to end this nonsense, and introduced the term "ionic liquids" for the first time. My M.Sc. Advisor in Chemical Metallurgy at Melbourne University, Mervyn Willis, told me this was the way to go, so I dropped the PbO-FeO-Fe2O 3-SiO2 4D phase diagram project I had been working on and joined Bockris' group (now at Penn) in 1956. That started a long journey through liquid silicates, molten salts, concentrated aqueous and non-aqueous solutions and back to ionic liquids, touching many personalities and countries, about which I would like to tell something. We take this opportunity to bring together in the same document, two fundamental energy level diagrams (4 decades apart in their development) that deal with the ionic liquid states of electrons, on the one hand, and protons, on the other.
AB - In the 1950's the literature on liquid silicates was mostly concerned with their function as scavengers for unwanted components in the metals extraction process. The slags were described as collections of oxide molecules. Then John Bockris, at Imperial College of Science, London, entered the scene to end this nonsense, and introduced the term "ionic liquids" for the first time. My M.Sc. Advisor in Chemical Metallurgy at Melbourne University, Mervyn Willis, told me this was the way to go, so I dropped the PbO-FeO-Fe2O 3-SiO2 4D phase diagram project I had been working on and joined Bockris' group (now at Penn) in 1956. That started a long journey through liquid silicates, molten salts, concentrated aqueous and non-aqueous solutions and back to ionic liquids, touching many personalities and countries, about which I would like to tell something. We take this opportunity to bring together in the same document, two fundamental energy level diagrams (4 decades apart in their development) that deal with the ionic liquid states of electrons, on the one hand, and protons, on the other.
UR - http://www.scopus.com/inward/record.url?scp=79952648533&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79952648533&partnerID=8YFLogxK
U2 - 10.1149/1.3484757
DO - 10.1149/1.3484757
M3 - Conference contribution
AN - SCOPUS:79952648533
SN - 9781566778268
T3 - ECS Transactions
SP - 3
EP - 18
BT - Molten Salts and Ionic Liquids 17
PB - Electrochemical Society Inc.
Y2 - 10 October 2010 through 15 October 2010
ER -