Fourier-transform spectroscopy of 13C17O and deperturbation analysis of the A1Π (υ=0–3) levels

R. Hakalla, M. L. Niu, R. W. Field, A. N. Heays, E. J. Salumbides, G. Stark, James Lyons, M. Eidelsberg, J. L. Lemaire, S. R. Federman, N. de Oliveira, W. Ubachs

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Abstract

The high-resolution B1Σ+→A1Π (0, 0) and (0, 3) emission bands of the less-abundant 13C17O isotopologue have been investigated by Fourier-transform spectroscopy in the visible region using a Bruker IFS 125HR spectrometer at an accuracy 0.003 cm-1. These spectra are combined with high-resolution photoabsorption measurements of the 13C17O B1Σ+←X1Σ+ (0, 0), B1Σ+←X1Σ+ (1, 0) and C1Σ+←X1Σ+ (0, 0) bands recorded with an accuracy of 0.01 cm-1 using the vacuum ultraviolet Fourier-transform spectrometer, installed on the DESIRS beamline at the SOLEIL synchrotron. In the studied 17,950–22,500 cm-1 and 86,800–92,100 cm-1 regions, 480 transitions have been measured. These new experimental data were combined with data from the C→A and B→A systems, previously analyzed in 13C17O. The frequencies of 1003 transitions derived from 12 bands were used to analyze the perturbations between the A1Π (υ=0–3) levels and rovibrational levels of the d3Δi, e3Σ-, a'3Σ+, I1Σ- and D1Δ states as well as to a preliminary investigation of weak irregularities that appear in the B1Σ+ (υ=0) level. Deperturbed molecular constants and term values of the A1Π state were obtained. The spin-orbit and L-uncoupling interaction parameters as well as isotopologue-independent spin-orbit and rotation-electronic perturbation parameters were derived.

Original languageEnglish (US)
Pages (from-to)312-328
Number of pages17
JournalJournal of Quantitative Spectroscopy and Radiative Transfer
Volume189
DOIs
StatePublished - Mar 1 2017

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Keywords

  • CO isotopologue
  • Carbon monoxide
  • FT-spectroscopy
  • High resolution VUV–VIS spectra
  • Perturbation analysis

ASJC Scopus subject areas

  • Radiation
  • Atomic and Molecular Physics, and Optics
  • Spectroscopy

Cite this

Hakalla, R., Niu, M. L., Field, R. W., Heays, A. N., Salumbides, E. J., Stark, G., Lyons, J., Eidelsberg, M., Lemaire, J. L., Federman, S. R., de Oliveira, N., & Ubachs, W. (2017). Fourier-transform spectroscopy of 13C17O and deperturbation analysis of the A1Π (υ=0–3) levels. Journal of Quantitative Spectroscopy and Radiative Transfer, 189, 312-328. https://doi.org/10.1016/j.jqsrt.2016.12.012