Formation of new polymorphs and control of crystallization in molecular glass-formers by electric field

K. Adrjanowicz, M. Paluch, Ranko Richert

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Static electric fields were observed to modify the crystallization behavior in a simple supercooled liquid, leading to a new crystal polymorph that could not be obtained in the absence of a field, even under high-pressure conditions. Using different thermal protocols and field amplitudes in the range from 40 to 200 kV cm-1, changes in both nucleation and crystal growth rates of 4-vinyl-propylene carbonate (vinyl-PC) are revealed. Remarkably, all field-induced changes in the crystallization behaviour were found to be fully reversible and do not affect dynamics of the tested liquid. Because vinyl-PC is a simple polar molecule, these field induced features are expected to occur in many other materials having permanent dipole moments. Our results highlight the important role of an external electric field as an additional control variable to influence the crystallization tendency of molecular glass-formers, and provide new opportunities in pharmaceutical science or organic electronics.

Original languageEnglish (US)
Pages (from-to)925-931
Number of pages7
JournalPhysical Chemistry Chemical Physics
Volume20
Issue number2
DOIs
StatePublished - Jan 1 2018

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Crystallization
Polymorphism
Electric fields
crystallization
propylene
Glass
electric fields
glass
carbonates
liquids
crystal growth
Dipole moment
Liquids
tendencies
dipole moments
nucleation
Nucleation
Electronic equipment
electronics
Crystals

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Formation of new polymorphs and control of crystallization in molecular glass-formers by electric field. / Adrjanowicz, K.; Paluch, M.; Richert, Ranko.

In: Physical Chemistry Chemical Physics, Vol. 20, No. 2, 01.01.2018, p. 925-931.

Research output: Contribution to journalArticle

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