Abstract
The absolute dynamics of the contact and the solvent-separated radical-ion pairs for a series of 2,6,9,10-tetracyanoanthracene acceptor/alkylbenzene donor systems have been determined in acetonitrile from a combined analysis of time-resolved excited charge-transfer emission and radical-ion pair absorption data and measurements of the quantum yields for formation of separated radical ions. Absolute rate data for the contact radical-ion pairs are obtained from time-resolved emission experiments. Absolute rate data for the solvent-separated radical-ion pairs are obtained for those cases in which the time-resolved emission is different from the time-resolved absorption.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 7635-7640 |
| Number of pages | 6 |
| Journal | Journal of physical chemistry |
| Volume | 96 |
| Issue number | 19 |
| DOIs | |
| State | Published - 1992 |
| Externally published | Yes |
ASJC Scopus subject areas
- General Engineering
- Physical and Theoretical Chemistry