TY - JOUR
T1 - Field Investigations of Chemical Partitioning and Aqueous Chemistry of Freezing Closed-Basin Lakes in Mongolia as Analogs of Subsurface Brines on Icy Bodies
AU - Yoda, Masahiro
AU - Sekine, Yasuhito
AU - Fukushi, Keisuke
AU - Kitajima, Takuma
AU - Gankhurel, Baasansuren
AU - Davaasuren, Davaadorj
AU - Gerelmaa, Tuvshin
AU - Ganbat, Shuukhaaz
AU - Shoji, Daigo
AU - Zolotov, Mikhail Y.
AU - Takahashi, Yoshio
N1 - Funding Information:
This study was supported by Grants‐in‐Aid for Scientific Research (KAKENHI JSPS Grants JP17H06456, JP17H06458, and JP20H00195), and the Joint Research programs of the Institute of Nature and Environmental Technology, Kanazawa University (Grants 19035, 20010, and 20059). We thank the drivers and local people for their help during the field surveys in cold seasons. M.Y. thanks O. Altansukh of the National University of Mongolia for storage of the ice samples. M.Y. also thanks Y. Takeichi of the Photon Factory, High Energy Accelerator Research Organization, KEK, for the experimental support with the X‐ray absorption near‐edge structure analysis. We are grateful for comments from two anonymous reviewers, which greatly improve the manuscript.
Funding Information:
This study was supported by Grants-in-Aid for Scientific Research (KAKENHI JSPS Grants JP17H06456, JP17H06458, and JP20H00195), and the Joint Research programs of the Institute of Nature and Environmental Technology, Kanazawa University (Grants 19035, 20010, and 20059). We thank the drivers and local people for their help during the field surveys in cold seasons. M.Y. thanks O. Altansukh of the National University of Mongolia for storage of the ice samples. M.Y. also thanks Y. Takeichi of the Photon Factory, High Energy Accelerator Research Organization, KEK, for the experimental support with the X-ray absorption near-edge structure analysis. We are grateful for comments from two anonymous reviewers, which greatly improve the manuscript.
Publisher Copyright:
© 2021. American Geophysical Union. All Rights Reserved.
PY - 2021/11
Y1 - 2021/11
N2 - Several icy bodies (e.g., Europa and Ceres) likely possess near-surface brine reservoirs, which are considered to be sources of salts on their surfaces. Previous studies have proposed processes whereby an overlying ice layer captures salinity from a freezing, subsurface reservoir. However, few field investigations have been conducted to investigate chemical partitioning and aqueous chemistry in freezing brine reservoirs in terrestrial analogs. Here we report results of winter field surveys to ice-covered, closed-basin saline lakes in the Valley of the Gobi Lakes, Mongolia. We found that the surface ice exhibited complex features, including both pressure ridges formed by compressive forces and wet cracks formed by tensile forces. The latter provides salinity to the ice layer and surface. In addition to wet cracks, saline lake bottom-water, along with suspended matter, was continuously captured within the pores of the ice layer during downward freezing. Using a combined mass balance and low-temperature aqueous chemistry model, we reproduced the ice salinity due to entrapment of Na+, Cl−, and SO42−, suggesting that chemical partitioning of these species in freezing brine reservoirs on icy bodies can be understood based on our current knowledge. In the lake bottom-water, the metastable phase of carbonates (i.e., amorphous Mg-carbonate and monohydrocalcite) play key roles in controlling the concentrations of precipitable Mg2+ and Ca2+ and alkalinity, highlighting the importance of metastable phase of carbonate in the aqueous chemistry of subsurface brine reservoirs on icy bodies. Metastable phases might be indicators of freshly erupted materials from brine reservoirs.
AB - Several icy bodies (e.g., Europa and Ceres) likely possess near-surface brine reservoirs, which are considered to be sources of salts on their surfaces. Previous studies have proposed processes whereby an overlying ice layer captures salinity from a freezing, subsurface reservoir. However, few field investigations have been conducted to investigate chemical partitioning and aqueous chemistry in freezing brine reservoirs in terrestrial analogs. Here we report results of winter field surveys to ice-covered, closed-basin saline lakes in the Valley of the Gobi Lakes, Mongolia. We found that the surface ice exhibited complex features, including both pressure ridges formed by compressive forces and wet cracks formed by tensile forces. The latter provides salinity to the ice layer and surface. In addition to wet cracks, saline lake bottom-water, along with suspended matter, was continuously captured within the pores of the ice layer during downward freezing. Using a combined mass balance and low-temperature aqueous chemistry model, we reproduced the ice salinity due to entrapment of Na+, Cl−, and SO42−, suggesting that chemical partitioning of these species in freezing brine reservoirs on icy bodies can be understood based on our current knowledge. In the lake bottom-water, the metastable phase of carbonates (i.e., amorphous Mg-carbonate and monohydrocalcite) play key roles in controlling the concentrations of precipitable Mg2+ and Ca2+ and alkalinity, highlighting the importance of metastable phase of carbonate in the aqueous chemistry of subsurface brine reservoirs on icy bodies. Metastable phases might be indicators of freshly erupted materials from brine reservoirs.
KW - cold aqueous chemistry
KW - icy body
KW - metastable carbonate
KW - subsurface brine reservoir
KW - terrestrial analog
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U2 - 10.1029/2021JE006972
DO - 10.1029/2021JE006972
M3 - Article
AN - SCOPUS:85119831639
SN - 2169-9097
VL - 126
JO - Journal of Geophysical Research: Planets
JF - Journal of Geophysical Research: Planets
IS - 11
M1 - e2021JE006972
ER -