Field emission from nitrogen-doped diamond film

M. Park, L. Bergman, W. B. Choi, A. T. Sowers, Robert Nemanich, J. J. Hren, J. J. Cuomo

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Nitrogen-doped diamond films were prepared for the first time using melamine (C 3H 6N 6) as the nitrogen source. To explore the differences in the films produced with different precursors, nitrogen-doped films were also produced using pure nitrogen gas as the source. Since melamine has a ring structure with pre-existing C-N bonds, the incorporation of nitrogen on substitutional sites of diamond lattice are expected. Relatively large amounts of substitutional nitrogen were successfully doped into diamond without degrading its quality. However, when pure nitrogen gas was used as a doping source, the quality of the diamond was not as high as the sample doped with nitrogen by melamine. Raman spectroscopy, photoluminescence spectroscopy (PL), and field emission measurements were carried out to characterize the samples. Nitrogen-doped diamond samples did not exhibit any significant reduction in turn-on fields. It is suggested that nitrogen doping has only a minor effect on the field emission properties of the diamond films.

Original languageEnglish (US)
Title of host publicationMaterials Research Society Symposium - Proceedings
PublisherMRS
Pages239-244
Number of pages6
Volume498
StatePublished - 1997
Externally publishedYes
EventProceedings of the 1997 MRS Fall Symposium - Boston, MA, USA
Duration: Dec 1 1997Dec 4 1997

Other

OtherProceedings of the 1997 MRS Fall Symposium
CityBoston, MA, USA
Period12/1/9712/4/97

Fingerprint

Diamond films
Field emission
Nitrogen
Diamond
Melamine
Diamonds
Gases
Doping (additives)
Photoluminescence spectroscopy
Raman spectroscopy

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Park, M., Bergman, L., Choi, W. B., Sowers, A. T., Nemanich, R., Hren, J. J., & Cuomo, J. J. (1997). Field emission from nitrogen-doped diamond film. In Materials Research Society Symposium - Proceedings (Vol. 498, pp. 239-244). MRS.

Field emission from nitrogen-doped diamond film. / Park, M.; Bergman, L.; Choi, W. B.; Sowers, A. T.; Nemanich, Robert; Hren, J. J.; Cuomo, J. J.

Materials Research Society Symposium - Proceedings. Vol. 498 MRS, 1997. p. 239-244.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Park, M, Bergman, L, Choi, WB, Sowers, AT, Nemanich, R, Hren, JJ & Cuomo, JJ 1997, Field emission from nitrogen-doped diamond film. in Materials Research Society Symposium - Proceedings. vol. 498, MRS, pp. 239-244, Proceedings of the 1997 MRS Fall Symposium, Boston, MA, USA, 12/1/97.
Park M, Bergman L, Choi WB, Sowers AT, Nemanich R, Hren JJ et al. Field emission from nitrogen-doped diamond film. In Materials Research Society Symposium - Proceedings. Vol. 498. MRS. 1997. p. 239-244
Park, M. ; Bergman, L. ; Choi, W. B. ; Sowers, A. T. ; Nemanich, Robert ; Hren, J. J. ; Cuomo, J. J. / Field emission from nitrogen-doped diamond film. Materials Research Society Symposium - Proceedings. Vol. 498 MRS, 1997. pp. 239-244
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AB - Nitrogen-doped diamond films were prepared for the first time using melamine (C 3H 6N 6) as the nitrogen source. To explore the differences in the films produced with different precursors, nitrogen-doped films were also produced using pure nitrogen gas as the source. Since melamine has a ring structure with pre-existing C-N bonds, the incorporation of nitrogen on substitutional sites of diamond lattice are expected. Relatively large amounts of substitutional nitrogen were successfully doped into diamond without degrading its quality. However, when pure nitrogen gas was used as a doping source, the quality of the diamond was not as high as the sample doped with nitrogen by melamine. Raman spectroscopy, photoluminescence spectroscopy (PL), and field emission measurements were carried out to characterize the samples. Nitrogen-doped diamond samples did not exhibit any significant reduction in turn-on fields. It is suggested that nitrogen doping has only a minor effect on the field emission properties of the diamond films.

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