Fast Li+ conduction in fluoroborate glasses

S. I. Smedley, Charles Angell

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Following recent measurements of very high d.c. conductivities in complex Li fluoride-borate-sulfate glasses, we have performed systematic measurements in the Li2OLiFB2O3 system. All glasses studied have essentially the same Arrhenius pre-exponential constant. Converting the data to conductivity relaxation times the pre-exponential constant corresponds to a frequency considerably higher than the Li+ - cage "rattling" frequency. Connections between the a.c. conductivity and the IR absorptivity are discussed.

Original languageEnglish (US)
Pages (from-to)421-425
Number of pages5
JournalMaterials Research Bulletin
Volume15
Issue number4
DOIs
StatePublished - 1980
Externally publishedYes

Fingerprint

conduction
Glass
conductivity
Borates
glass
Fluorides
Relaxation time
Sulfates
borates
fluorides
sulfates
absorptivity
relaxation time

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

Cite this

Fast Li+ conduction in fluoroborate glasses. / Smedley, S. I.; Angell, Charles.

In: Materials Research Bulletin, Vol. 15, No. 4, 1980, p. 421-425.

Research output: Contribution to journalArticle

Smedley, S. I. ; Angell, Charles. / Fast Li+ conduction in fluoroborate glasses. In: Materials Research Bulletin. 1980 ; Vol. 15, No. 4. pp. 421-425.
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