Facial selectivity in the cycloaddition of heterodienes to carbohydrate cyclic ketene acetals. A novel synthesis of disaccharide derivatives

Stephen C. Johnson, Curtis Crasto, Sidney M. Hecht

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

Carbohydrate ketene acetals derived from mannopyranose and glucopyranose are shown to serve as electron-rich dienophiles in facially selective, Lewis acid-catalyzed inverse electron demand hetero-Diels-Alder reactions.

Original languageEnglish (US)
Pages (from-to)1019-1020
Number of pages2
JournalChemical Communications
Issue number9
DOIs
StatePublished - May 7 1998
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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