Fabrication of cuprous nanoparticles in MIL-101: An efficient adsorbent for the separation of olefin-paraffin mixtures

Ganggang Chang; Zongbi Bao; Qilong Ren; Shuguang Deng; Zhiguo Zhang; Baogen Su; Huabin Xing; Yiwen Yang

doi:10.1039/c4ra02125h

Fabrication of cuprous nanoparticles in MIL-101: An efficient adsorbent for the separation of olefin-paraffin mixtures

Ganggang Chang, Zongbi Bao, Qilong Ren, Shuguang Deng, Zhiguo Zhang, Baogen Su, Huabin Xing, Yiwen Yang

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

Various amounts of Cu⁺ nanoparticles were successfully deposited to the pores of metal-organic frameworks MIL-101 with a double-solvent method. An optimized, cuprous-loaded MIL-101 was shown to have an enhanced ethylene adsorption capacity and higher ethylene-ethane selectivity (14.0), compared to pure MIL-101 (1.6). The great improvement in selectivity can be attributed to the newly generated nano-sized cuprous chloride particles that can selectively interact with the carbon-carbon double bond in ethylene through π-complexation. This journal is

Original language	English (US)
Pages (from-to)	20230-20233
Number of pages	4
Journal	RSC Advances
Volume	4
Issue number	39
DOIs	https://doi.org/10.1039/c4ra02125h
State	Published - 2014
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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T2 - An efficient adsorbent for the separation of olefin-paraffin mixtures

AU - Chang, Ganggang

AU - Bao, Zongbi

AU - Ren, Qilong

AU - Deng, Shuguang

AU - Zhang, Zhiguo

AU - Su, Baogen

AU - Xing, Huabin

AU - Yang, Yiwen

PY - 2014

Y1 - 2014

N2 - Various amounts of Cu+ nanoparticles were successfully deposited to the pores of metal-organic frameworks MIL-101 with a double-solvent method. An optimized, cuprous-loaded MIL-101 was shown to have an enhanced ethylene adsorption capacity and higher ethylene-ethane selectivity (14.0), compared to pure MIL-101 (1.6). The great improvement in selectivity can be attributed to the newly generated nano-sized cuprous chloride particles that can selectively interact with the carbon-carbon double bond in ethylene through π-complexation. This journal is

AB - Various amounts of Cu+ nanoparticles were successfully deposited to the pores of metal-organic frameworks MIL-101 with a double-solvent method. An optimized, cuprous-loaded MIL-101 was shown to have an enhanced ethylene adsorption capacity and higher ethylene-ethane selectivity (14.0), compared to pure MIL-101 (1.6). The great improvement in selectivity can be attributed to the newly generated nano-sized cuprous chloride particles that can selectively interact with the carbon-carbon double bond in ethylene through π-complexation. This journal is

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Fabrication of cuprous nanoparticles in MIL-101: An efficient adsorbent for the separation of olefin-paraffin mixtures

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