Fabrication of cuprous nanoparticles in MIL-101: An efficient adsorbent for the separation of olefin-paraffin mixtures

Ganggang Chang, Zongbi Bao, Qilong Ren, Shuguang Deng, Zhiguo Zhang, Baogen Su, Huabin Xing, Yiwen Yang

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

Various amounts of Cu+ nanoparticles were successfully deposited to the pores of metal-organic frameworks MIL-101 with a double-solvent method. An optimized, cuprous-loaded MIL-101 was shown to have an enhanced ethylene adsorption capacity and higher ethylene-ethane selectivity (14.0), compared to pure MIL-101 (1.6). The great improvement in selectivity can be attributed to the newly generated nano-sized cuprous chloride particles that can selectively interact with the carbon-carbon double bond in ethylene through π-complexation. This journal is

Original languageEnglish (US)
Pages (from-to)20230-20233
Number of pages4
JournalRSC Advances
Volume4
Issue number39
DOIs
StatePublished - 2014
Externally publishedYes

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Alkenes
Paraffin
Paraffins
Adsorbents
Olefins
Ethylene
Nanoparticles
Fabrication
Carbon
Ethane
Complexation
Metals
Adsorption
ethylene
MIL-101

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Fabrication of cuprous nanoparticles in MIL-101 : An efficient adsorbent for the separation of olefin-paraffin mixtures. / Chang, Ganggang; Bao, Zongbi; Ren, Qilong; Deng, Shuguang; Zhang, Zhiguo; Su, Baogen; Xing, Huabin; Yang, Yiwen.

In: RSC Advances, Vol. 4, No. 39, 2014, p. 20230-20233.

Research output: Contribution to journalArticle

Chang, Ganggang ; Bao, Zongbi ; Ren, Qilong ; Deng, Shuguang ; Zhang, Zhiguo ; Su, Baogen ; Xing, Huabin ; Yang, Yiwen. / Fabrication of cuprous nanoparticles in MIL-101 : An efficient adsorbent for the separation of olefin-paraffin mixtures. In: RSC Advances. 2014 ; Vol. 4, No. 39. pp. 20230-20233.
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AU - Xing, Huabin

AU - Yang, Yiwen

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