Exchange interactions in some low-dimensional metal dithiolene complexes

P. Kuppusamy; B. L. Ramakrishna; P. T. Manoharan

doi:10.1007/BF02840341

Exchange interactions in some low-dimensional metal dithiolene complexes

P. Kuppusamy, B. L. Ramakrishna, P. T. Manoharan

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Low-dimensional systems are formed by planar metal dithiolene complexes which stack as columnar structures in the solid state. Stronger interactions among units within a chain leads to highly anisotropic magnetic properties. The magnetic effects are a manifestation of exchange interaction, J and can be studied through detailed epr techniques in conjunction with magnetic susceptibility and x-ray crystal structure. A brief review of such studies carried out mostly in our laboratory is presented along with the relevant background materials.

Original language	English (US)
Pages (from-to)	977-1001
Number of pages	25
Journal	Proceedings of the Indian Academy of Sciences - Chemical Sciences
Volume	93
Issue number	6
DOIs	https://doi.org/10.1007/BF02840341
State	Published - Aug 1984
Externally published	Yes

Keywords

Metal dithiolenes
electron paramagnetic resonance
exchange interactions
low-dimensional systems
magnetic susceptibility
x-ray crystal structure

ASJC Scopus subject areas

General Chemistry

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10.1007/BF02840341

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abstract = "Low-dimensional systems are formed by planar metal dithiolene complexes which stack as columnar structures in the solid state. Stronger interactions among units within a chain leads to highly anisotropic magnetic properties. The magnetic effects are a manifestation of exchange interaction, J and can be studied through detailed epr techniques in conjunction with magnetic susceptibility and x-ray crystal structure. A brief review of such studies carried out mostly in our laboratory is presented along with the relevant background materials.",

keywords = "Metal dithiolenes, electron paramagnetic resonance, exchange interactions, low-dimensional systems, magnetic susceptibility, x-ray crystal structure",

author = "P. Kuppusamy and Ramakrishna, {B. L.} and Manoharan, {P. T.}",

year = "1984",

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volume = "93",

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AU - Ramakrishna, B. L.

AU - Manoharan, P. T.

PY - 1984/8

Y1 - 1984/8

N2 - Low-dimensional systems are formed by planar metal dithiolene complexes which stack as columnar structures in the solid state. Stronger interactions among units within a chain leads to highly anisotropic magnetic properties. The magnetic effects are a manifestation of exchange interaction, J and can be studied through detailed epr techniques in conjunction with magnetic susceptibility and x-ray crystal structure. A brief review of such studies carried out mostly in our laboratory is presented along with the relevant background materials.

AB - Low-dimensional systems are formed by planar metal dithiolene complexes which stack as columnar structures in the solid state. Stronger interactions among units within a chain leads to highly anisotropic magnetic properties. The magnetic effects are a manifestation of exchange interaction, J and can be studied through detailed epr techniques in conjunction with magnetic susceptibility and x-ray crystal structure. A brief review of such studies carried out mostly in our laboratory is presented along with the relevant background materials.

KW - Metal dithiolenes

KW - electron paramagnetic resonance

KW - exchange interactions

KW - low-dimensional systems

KW - magnetic susceptibility

KW - x-ray crystal structure

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JF - Proceedings of the Indian Academy of Sciences - Chemical Sciences

IS - 6

ER -

Exchange interactions in some low-dimensional metal dithiolene complexes

Abstract

Keywords

ASJC Scopus subject areas

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