Exchange interactions in bis(diethyldithiocarbamato)copper(II), Cu(detc)2

B. L. Ramakrishna; P. T. Manoharan

doi:10.1016/0009-2614(83)87192-9

Exchange interactions in bis(diethyldithiocarbamato)copper(II), Cu(detc)₂

B. L. Ramakrishna, P. T. Manoharan

Engineering of Matter, Transport and Energy, School for (IAFSE-SEMTE)

Research output: Contribution to journal › Article › peer-review

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Abstract

The exchange coupling constant J in bis(diethyldithiocarbamato)copper(II) has been derived through analysis of the EPR g values and linewidth as a function of orientation, frequency and temperature. The single line in the ac* plane is due to the averaging of the fine-structure splitting by interdimer exchange for which a lower limit of 0.02 cm^-1 has been obtained. Analysis of the spectra in the bc plane gives an estimate of 0.008 cm^-1 for the intersite exchange.

Original language	English (US)
Pages (from-to)	98-102
Number of pages	5
Journal	Chemical Physics Letters
Volume	97
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(83)87192-9
State	Published - May 6 1983

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General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "Exchange interactions in bis(diethyldithiocarbamato)copper(II), Cu(detc)2",

abstract = "The exchange coupling constant J in bis(diethyldithiocarbamato)copper(II) has been derived through analysis of the EPR g values and linewidth as a function of orientation, frequency and temperature. The single line in the ac* plane is due to the averaging of the fine-structure splitting by interdimer exchange for which a lower limit of 0.02 cm-1 has been obtained. Analysis of the spectra in the bc plane gives an estimate of 0.008 cm-1 for the intersite exchange.",

author = "Ramakrishna, {B. L.} and Manoharan, {P. T.}",

note = "Funding Information: We are grateful to the Fonds der Chemischen Indus-trie and the BASF Aktiengesellschaft in LudwiSshafen for financial Support.",

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doi = "10.1016/0009-2614(83)87192-9",

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T1 - Exchange interactions in bis(diethyldithiocarbamato)copper(II), Cu(detc)2

AU - Ramakrishna, B. L.

AU - Manoharan, P. T.

N1 - Funding Information: We are grateful to the Fonds der Chemischen Indus-trie and the BASF Aktiengesellschaft in LudwiSshafen for financial Support.

PY - 1983/5/6

Y1 - 1983/5/6

N2 - The exchange coupling constant J in bis(diethyldithiocarbamato)copper(II) has been derived through analysis of the EPR g values and linewidth as a function of orientation, frequency and temperature. The single line in the ac* plane is due to the averaging of the fine-structure splitting by interdimer exchange for which a lower limit of 0.02 cm-1 has been obtained. Analysis of the spectra in the bc plane gives an estimate of 0.008 cm-1 for the intersite exchange.

AB - The exchange coupling constant J in bis(diethyldithiocarbamato)copper(II) has been derived through analysis of the EPR g values and linewidth as a function of orientation, frequency and temperature. The single line in the ac* plane is due to the averaging of the fine-structure splitting by interdimer exchange for which a lower limit of 0.02 cm-1 has been obtained. Analysis of the spectra in the bc plane gives an estimate of 0.008 cm-1 for the intersite exchange.

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ER -

Exchange interactions in bis(diethyldithiocarbamato)copper(II), Cu(detc)₂

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