Exchange interactions in bis(diethyldithiocarbamato)copper(II), Cu(detc)2

B. L. Ramakrishna, P. T. Manoharan

Research output: Contribution to journalArticle

1 Scopus citations

Abstract

The exchange coupling constant J in bis(diethyldithiocarbamato)copper(II) has been derived through analysis of the EPR g values and linewidth as a function of orientation, frequency and temperature. The single line in the ac* plane is due to the averaging of the fine-structure splitting by interdimer exchange for which a lower limit of 0.02 cm-1 has been obtained. Analysis of the spectra in the bc plane gives an estimate of 0.008 cm-1 for the intersite exchange.

Original languageEnglish (US)
Pages (from-to)98-102
Number of pages5
JournalChemical Physics Letters
Volume97
Issue number1
DOIs
StatePublished - May 6 1983

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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