Evaluation of the adamantyl effect on vinyl polymer T g

Hawa Yazci Acar, Jennifer Jensen, Kevin Thigpen, John McGowen, Demetrius McCormick, Louis Somlai, J. Lan

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Incorporation of adamantane as a pendant group increases the glass transition temperature (T g) of the parent polymer significantly for both condensation polymers and vinyl polymers. although it is intuitive that large pendant groups tend to have such an effect due to the reduced chain mobility, the magnitude of increase is surprisingly high for adamantane. The effects of adamantane substitution on physical, thermal and mechanical properties of a variety of polymer families ranging from acrylates to phenolics are analyzed. Methacrylate esters with different spacers varying in length and rigidity, phenyl and methyl, between the adamantane and the backbone are analyzed. Homopolymers and copolymers of both monomers with styrene are synthesized.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
PublisherACS
Pages620-621
Number of pages2
Volume40
Edition2
StatePublished - Aug 1999
Externally publishedYes

Fingerprint

Adamantane
Polymers
Acrylates
Styrene
Methacrylates
Homopolymerization
Rigidity
Condensation
Esters
Substitution reactions
Thermodynamic properties
Copolymers
Physical properties
Monomers
Mechanical properties

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Acar, H. Y., Jensen, J., Thigpen, K., McGowen, J., McCormick, D., Somlai, L., & Lan, J. (1999). Evaluation of the adamantyl effect on vinyl polymer T g In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (2 ed., Vol. 40, pp. 620-621). ACS.

Evaluation of the adamantyl effect on vinyl polymer T g . / Acar, Hawa Yazci; Jensen, Jennifer; Thigpen, Kevin; McGowen, John; McCormick, Demetrius; Somlai, Louis; Lan, J.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 40 2. ed. ACS, 1999. p. 620-621.

Research output: Chapter in Book/Report/Conference proceedingChapter

Acar, HY, Jensen, J, Thigpen, K, McGowen, J, McCormick, D, Somlai, L & Lan, J 1999, Evaluation of the adamantyl effect on vinyl polymer T g in American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 edn, vol. 40, ACS, pp. 620-621.
Acar HY, Jensen J, Thigpen K, McGowen J, McCormick D, Somlai L et al. Evaluation of the adamantyl effect on vinyl polymer T g In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 ed. Vol. 40. ACS. 1999. p. 620-621
Acar, Hawa Yazci ; Jensen, Jennifer ; Thigpen, Kevin ; McGowen, John ; McCormick, Demetrius ; Somlai, Louis ; Lan, J. / Evaluation of the adamantyl effect on vinyl polymer T g American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 40 2. ed. ACS, 1999. pp. 620-621
@inbook{a01b79eaaf0a489aadde2329353ff842,
title = "Evaluation of the adamantyl effect on vinyl polymer T g",
abstract = "Incorporation of adamantane as a pendant group increases the glass transition temperature (T g) of the parent polymer significantly for both condensation polymers and vinyl polymers. although it is intuitive that large pendant groups tend to have such an effect due to the reduced chain mobility, the magnitude of increase is surprisingly high for adamantane. The effects of adamantane substitution on physical, thermal and mechanical properties of a variety of polymer families ranging from acrylates to phenolics are analyzed. Methacrylate esters with different spacers varying in length and rigidity, phenyl and methyl, between the adamantane and the backbone are analyzed. Homopolymers and copolymers of both monomers with styrene are synthesized.",
author = "Acar, {Hawa Yazci} and Jennifer Jensen and Kevin Thigpen and John McGowen and Demetrius McCormick and Louis Somlai and J. Lan",
year = "1999",
month = "8",
language = "English (US)",
volume = "40",
pages = "620--621",
booktitle = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",
publisher = "ACS",
edition = "2",

}

TY - CHAP

T1 - Evaluation of the adamantyl effect on vinyl polymer T g

AU - Acar, Hawa Yazci

AU - Jensen, Jennifer

AU - Thigpen, Kevin

AU - McGowen, John

AU - McCormick, Demetrius

AU - Somlai, Louis

AU - Lan, J.

PY - 1999/8

Y1 - 1999/8

N2 - Incorporation of adamantane as a pendant group increases the glass transition temperature (T g) of the parent polymer significantly for both condensation polymers and vinyl polymers. although it is intuitive that large pendant groups tend to have such an effect due to the reduced chain mobility, the magnitude of increase is surprisingly high for adamantane. The effects of adamantane substitution on physical, thermal and mechanical properties of a variety of polymer families ranging from acrylates to phenolics are analyzed. Methacrylate esters with different spacers varying in length and rigidity, phenyl and methyl, between the adamantane and the backbone are analyzed. Homopolymers and copolymers of both monomers with styrene are synthesized.

AB - Incorporation of adamantane as a pendant group increases the glass transition temperature (T g) of the parent polymer significantly for both condensation polymers and vinyl polymers. although it is intuitive that large pendant groups tend to have such an effect due to the reduced chain mobility, the magnitude of increase is surprisingly high for adamantane. The effects of adamantane substitution on physical, thermal and mechanical properties of a variety of polymer families ranging from acrylates to phenolics are analyzed. Methacrylate esters with different spacers varying in length and rigidity, phenyl and methyl, between the adamantane and the backbone are analyzed. Homopolymers and copolymers of both monomers with styrene are synthesized.

UR - http://www.scopus.com/inward/record.url?scp=0032676933&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032676933&partnerID=8YFLogxK

M3 - Chapter

AN - SCOPUS:0032676933

VL - 40

SP - 620

EP - 621

BT - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

PB - ACS

ER -