Enthalpies of formation of some tungstates, MWO4

A. Navrotsky; O. J. Kleppa

doi:10.1021/ic50074a011

Enthalpies of formation of some tungstates, MWO₄

A. Navrotsky, O. J. Kleppa

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Abstract

The enthalpies of formation of the isostructural tungstates MWO₄ (M = Mg, Co, Ni, Cu, Zn, Cd) were determined by solution calorimetry in a 3Na₂O.4MoO₃ melt at 970°K. Regularities in the heats of formation are compared with those observed for spinels, sulfates, and carbonates of the same cations.

Original language	English (US)
Pages (from-to)	756-758
Number of pages	3
Journal	Inorganic chemistry
Volume	8
Issue number	4
DOIs	https://doi.org/10.1021/ic50074a011
State	Published - Apr 1 1969
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic50074a011

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title = "Enthalpies of formation of some tungstates, MWO4",

abstract = "The enthalpies of formation of the isostructural tungstates MWO4 (M = Mg, Co, Ni, Cu, Zn, Cd) were determined by solution calorimetry in a 3Na2O.4MoO3 melt at 970°K. Regularities in the heats of formation are compared with those observed for spinels, sulfates, and carbonates of the same cations.",

author = "A. Navrotsky and Kleppa, {O. J.}",

year = "1969",

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N2 - The enthalpies of formation of the isostructural tungstates MWO4 (M = Mg, Co, Ni, Cu, Zn, Cd) were determined by solution calorimetry in a 3Na2O.4MoO3 melt at 970°K. Regularities in the heats of formation are compared with those observed for spinels, sulfates, and carbonates of the same cations.

AB - The enthalpies of formation of the isostructural tungstates MWO4 (M = Mg, Co, Ni, Cu, Zn, Cd) were determined by solution calorimetry in a 3Na2O.4MoO3 melt at 970°K. Regularities in the heats of formation are compared with those observed for spinels, sulfates, and carbonates of the same cations.

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Enthalpies of formation of some tungstates, MWO₄

Abstract

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