Abstract
As-synthesized Ni-based Lewis acidic catalysts, with tunable concentrations of β-Ni(OH) 2 and γ-NiOOH, were tested on the conversion of sugars to methyl lactate (MLA) in near-critical methanol solutions. The concentration of γ-NiOOH increased with an increase in the Ni(NO 3 ) 2 ·6H 2 O/2-methylimidazole (Ni/2-Hmim) molar ratio. Compared to β-Ni(OH) 2 , the γ-NiOOH showed more mesopores in the catalyst, which facilitated the diffusion of reactant and products. Ni/2-Hmim-4 [Ni(NO 3 ) 2 ·6H 2 O/2-methylimidazole molar ratio = 4] exhibited the best catalytic activity. Under optimal conditions (180 °C for 12 h), the highest MLA yield was 41.9% on the conversion of glucose. Ni/2-Hmim-4 was employed to convert disaccharides to MLA. Notably, for sucrose, the reaction afforded a 38.7% MLA yield at 200 °C for 12 h. The catalyst was reusable for at least three cycles.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 3659-3665 |
| Number of pages | 7 |
| Journal | Industrial and Engineering Chemistry Research |
| Volume | 58 |
| Issue number | 9 |
| DOIs | |
| State | Published - Mar 6 2019 |
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ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)
- Industrial and Manufacturing Engineering
Cite this
Enhancement of Catalytic Activity by γ-NiOOH for the Production of Methyl Lactate from Sugars in Near-Critical Methanol Solutions. / Lyu, Xilei; Wang, Lixin; Chen, Xujie; Xu, Ling; Wang, Juncheng; Deng, Shuguang; Lu, Xiuyang.
In: Industrial and Engineering Chemistry Research, Vol. 58, No. 9, 06.03.2019, p. 3659-3665.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Enhancement of Catalytic Activity by γ-NiOOH for the Production of Methyl Lactate from Sugars in Near-Critical Methanol Solutions
AU - Lyu, Xilei
AU - Wang, Lixin
AU - Chen, Xujie
AU - Xu, Ling
AU - Wang, Juncheng
AU - Deng, Shuguang
AU - Lu, Xiuyang
PY - 2019/3/6
Y1 - 2019/3/6
N2 - As-synthesized Ni-based Lewis acidic catalysts, with tunable concentrations of β-Ni(OH) 2 and γ-NiOOH, were tested on the conversion of sugars to methyl lactate (MLA) in near-critical methanol solutions. The concentration of γ-NiOOH increased with an increase in the Ni(NO 3 ) 2 ·6H 2 O/2-methylimidazole (Ni/2-Hmim) molar ratio. Compared to β-Ni(OH) 2 , the γ-NiOOH showed more mesopores in the catalyst, which facilitated the diffusion of reactant and products. Ni/2-Hmim-4 [Ni(NO 3 ) 2 ·6H 2 O/2-methylimidazole molar ratio = 4] exhibited the best catalytic activity. Under optimal conditions (180 °C for 12 h), the highest MLA yield was 41.9% on the conversion of glucose. Ni/2-Hmim-4 was employed to convert disaccharides to MLA. Notably, for sucrose, the reaction afforded a 38.7% MLA yield at 200 °C for 12 h. The catalyst was reusable for at least three cycles.
AB - As-synthesized Ni-based Lewis acidic catalysts, with tunable concentrations of β-Ni(OH) 2 and γ-NiOOH, were tested on the conversion of sugars to methyl lactate (MLA) in near-critical methanol solutions. The concentration of γ-NiOOH increased with an increase in the Ni(NO 3 ) 2 ·6H 2 O/2-methylimidazole (Ni/2-Hmim) molar ratio. Compared to β-Ni(OH) 2 , the γ-NiOOH showed more mesopores in the catalyst, which facilitated the diffusion of reactant and products. Ni/2-Hmim-4 [Ni(NO 3 ) 2 ·6H 2 O/2-methylimidazole molar ratio = 4] exhibited the best catalytic activity. Under optimal conditions (180 °C for 12 h), the highest MLA yield was 41.9% on the conversion of glucose. Ni/2-Hmim-4 was employed to convert disaccharides to MLA. Notably, for sucrose, the reaction afforded a 38.7% MLA yield at 200 °C for 12 h. The catalyst was reusable for at least three cycles.
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U2 - 10.1021/acs.iecr.8b06367
DO - 10.1021/acs.iecr.8b06367
M3 - Article
VL - 58
SP - 3659
EP - 3665
JO - Industrial & Engineering Chemistry Research
JF - Industrial & Engineering Chemistry Research
SN - 0888-5885
IS - 9
ER -