Enhanced Wear Resistance of Transparent Epoxy Composite Coatings with Vertically Aligned Halloysite Nanotubes

Kenan Song, Dayong Chen, Roberta Polak, Michael F. Rubner, Robert E. Cohen, Khalid A. Askar

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The influence of nanoparticle orientation on wear resistance of transparent composite coatings has been studied. Using a nozzle spray coating method, halloysite nanotubes (HNTs) were aligned in the in-plane and out-of-plane directions and in various randomly oriented states. Nanoscratching, falling sand, and Taber Abrasion tests were used to characterize the wear resistance at different length scales. Composites consistently displayed better wear resistance than pure epoxy. Samples with out-of-plane particle orientations exhibited better wear-resistant behavior than those with in-plane particle distributions. In nanoscratching tests, the out-of-plane orientation decreases the normalized scratch volume by as much as 60% compared to pure epoxy. In the falling sand and Taber Abrasion tests, out-of-plane aligned halloysite particles resulted in surfaces with smaller roughness based on stylus profilometry and SEM observations. The decrease in roughness values after these wear tests can be as large as 67% from pure epoxy to composites. Composites with higher out-of-plane particle orientation factors exhibited better light transmittance after sand impingements and other wear tests. This study suggests a useful strategy for producing material systems with enhanced mechanical durability and more durable optical properties.

Original languageEnglish (US)
Pages (from-to)35552-35564
Number of pages13
JournalACS Applied Materials and Interfaces
Volume8
Issue number51
DOIs
StatePublished - Dec 28 2016
Externally publishedYes

Fingerprint

Composite coatings
Nanotubes
Wear resistance
Sand
Wear of materials
Abrasion
Composite materials
Surface roughness
Spray nozzles
Profilometry
Durability
Optical properties
Nanoparticles
Coatings
Scanning electron microscopy
clay

Keywords

  • alignment
  • composite
  • falling sand
  • HNTs
  • scratching
  • Taber Abrasion
  • transparent
  • wear

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Enhanced Wear Resistance of Transparent Epoxy Composite Coatings with Vertically Aligned Halloysite Nanotubes. / Song, Kenan; Chen, Dayong; Polak, Roberta; Rubner, Michael F.; Cohen, Robert E.; Askar, Khalid A.

In: ACS Applied Materials and Interfaces, Vol. 8, No. 51, 28.12.2016, p. 35552-35564.

Research output: Contribution to journalArticle

Song, Kenan ; Chen, Dayong ; Polak, Roberta ; Rubner, Michael F. ; Cohen, Robert E. ; Askar, Khalid A. / Enhanced Wear Resistance of Transparent Epoxy Composite Coatings with Vertically Aligned Halloysite Nanotubes. In: ACS Applied Materials and Interfaces. 2016 ; Vol. 8, No. 51. pp. 35552-35564.
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