Enhanced power conversion efficiency and preferential orientation of the MAPbI3 perovskite solar cells by introduction of urea as additive

Ying Li, Lingwei Li, Aditya S. Yerramilli, Yuanqing Chen, Daining Fang, Yuxia Shen, Terry Alford

Research output: Contribution to journalArticle

Abstract

In this investigation, urea (NH2CONH2) was added into the perovskite precursor solution with Pb(CH3COO)3 as precursor. The effects of the urea content in the solution on the crystallization dynamics and the orientation of the perovskite films, and their photovoltaic properties were investigated. The results showed that the optimal annealing duration for the perovskite film increased with the urea content in the solution. An interaction between the urea and the source materials was observed. As a result, urea addition in the Pb(CH3COO)3 based solution has an effect on the crystallization rate and the grain size of the perovskite phase. We found that the suitable amount of urea in the solution was beneficial for the formation of highly (110)-oriented perovskite films and this resulted in the corresponding solar cells with enhanced power conversion efficiency of nearly 17%.

Original languageEnglish (US)
Pages (from-to)130-136
Number of pages7
JournalOrganic Electronics: physics, materials, applications
Volume73
DOIs
StatePublished - Oct 1 2019
Externally publishedYes

Fingerprint

ureas
Urea
Conversion efficiency
Perovskite
solar cells
Crystallization
crystallization
Crystal orientation
Perovskite solar cells
Solar cells
grain size
perovskite
Annealing
annealing
interactions

Keywords

  • Crystallization dynamics
  • Perovskite
  • Power conversion efficiency
  • Solar cells

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry
  • Electrical and Electronic Engineering

Cite this

Enhanced power conversion efficiency and preferential orientation of the MAPbI3 perovskite solar cells by introduction of urea as additive. / Li, Ying; Li, Lingwei; Yerramilli, Aditya S.; Chen, Yuanqing; Fang, Daining; Shen, Yuxia; Alford, Terry.

In: Organic Electronics: physics, materials, applications, Vol. 73, 01.10.2019, p. 130-136.

Research output: Contribution to journalArticle

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AU - Li, Ying

AU - Li, Lingwei

AU - Yerramilli, Aditya S.

AU - Chen, Yuanqing

AU - Fang, Daining

AU - Shen, Yuxia

AU - Alford, Terry

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AB - In this investigation, urea (NH2CONH2) was added into the perovskite precursor solution with Pb(CH3COO)3 as precursor. The effects of the urea content in the solution on the crystallization dynamics and the orientation of the perovskite films, and their photovoltaic properties were investigated. The results showed that the optimal annealing duration for the perovskite film increased with the urea content in the solution. An interaction between the urea and the source materials was observed. As a result, urea addition in the Pb(CH3COO)3 based solution has an effect on the crystallization rate and the grain size of the perovskite phase. We found that the suitable amount of urea in the solution was beneficial for the formation of highly (110)-oriented perovskite films and this resulted in the corresponding solar cells with enhanced power conversion efficiency of nearly 17%.

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