Engineering solar cells based on correlative X-ray microscopy

Michael Stuckelberger, Bradley West, Tara Nietzold, Barry Lai, Jörg M. Maser, Volker Rose, Mariana Bertoni

Research output: Contribution to journalReview article

15 Scopus citations

Abstract

In situ and operando measurement techniques combined with nanoscale resolution have proven invaluable in multiple fields of study. We argue that evaluating device performance as well as material behavior by correlative X-ray microscopy with <100 nm resolution can radically change the approach for optimizing absorbers, interfaces and full devices in solar cell research. In this article, we thoroughly discuss the measurement technique of X-ray beam induced current and point out fundamental differences between measurements of wafer-based silicon and thin-film solar cells. Based on reports of the last years, we showcase the potential that X-ray microscopy measurements have in combination with in situ and operando approaches throughout the solar cell lifecycle: from the growth of individual layers to the performance under operating conditions and degradation mechanisms. Enabled by new developments in synchrotron beamlines, the combination of high spatial resolution with high brilliance and a safe working distance allows for the insertion of measurement equipment that can pave the way for a new class of experiments. Applied to photovoltaics research, we highlight today's opportunities and challenges in the field of nanoscale X-ray microscopy, and give an outlook on future developments.

Original languageEnglish (US)
Pages (from-to)1825-1854
Number of pages30
JournalJournal of Materials Research
Volume32
Issue number10
DOIs
StatePublished - May 26 2017

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Keywords

  • correlative microscopy
  • HXM
  • in situ
  • nanoscale
  • operando
  • photovoltaic
  • solar cells
  • X-ray fluorescence
  • X-ray microscopy

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Stuckelberger, M., West, B., Nietzold, T., Lai, B., Maser, J. M., Rose, V., & Bertoni, M. (2017). Engineering solar cells based on correlative X-ray microscopy. Journal of Materials Research, 32(10), 1825-1854. https://doi.org/10.1557/jmr.2017.108