TY - JOUR
T1 - End Capping Does Matter
T2 - Enhanced Order and Charge Transport in Conjugated Donor-Acceptor Polymers
AU - Koldemir, Unsal
AU - Puniredd, Sreenivasa Reddy
AU - Wagner, Manfred
AU - Tongay, Sefaattin
AU - McCarley, Tracy D.
AU - Kamenov, George Dimitrov
AU - Müllen, Klaus
AU - Pisula, Wojciech
AU - Reynolds, John R.
N1 - Publisher Copyright:
© 2015 American Chemical Society.
PY - 2015/9/22
Y1 - 2015/9/22
N2 - Optimized microstructure through control of both intra- and intermolecular interactions in organic semiconductors is critical for enhancing and optimizing charge transport for the realization of next-generation low-cost, mechanically flexible, and easy to process high performance, organic field effect transistors (OFETs). Herein, we report donor-acceptor alternating copolymers of dithienogermole (DTG) with 2,1,3-benzothiadiazole (BTD) and probe the importance of end groups on the control of molecular order and microstructure as it relates to the enhancement of charge carrier transport. Partial end-capping reactions, confirmed by 1H NMR and matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) analyses, on the DTG-BTD copolymer provided significant improvement in grazing incidence wide angle X-Ray scattering (GIWAXS) determined polymer ordering in thin films. Consequently, OFETs exhibited charge-carrier mobilities up to 0.60 cm2/(Vs) for the end-capped copolymer, which are an order of magnitude higher in comparison to the non-end-capped analogue, which displayed a mobility of 0.077 cm2/(Vs). We emphasize that a simple synthetic approach, the introduction of end-capping groups which remove reactive functionalities, can be effective in the development of next-generation OFET and solar materials by promising better control of the polymer organization.
AB - Optimized microstructure through control of both intra- and intermolecular interactions in organic semiconductors is critical for enhancing and optimizing charge transport for the realization of next-generation low-cost, mechanically flexible, and easy to process high performance, organic field effect transistors (OFETs). Herein, we report donor-acceptor alternating copolymers of dithienogermole (DTG) with 2,1,3-benzothiadiazole (BTD) and probe the importance of end groups on the control of molecular order and microstructure as it relates to the enhancement of charge carrier transport. Partial end-capping reactions, confirmed by 1H NMR and matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) analyses, on the DTG-BTD copolymer provided significant improvement in grazing incidence wide angle X-Ray scattering (GIWAXS) determined polymer ordering in thin films. Consequently, OFETs exhibited charge-carrier mobilities up to 0.60 cm2/(Vs) for the end-capped copolymer, which are an order of magnitude higher in comparison to the non-end-capped analogue, which displayed a mobility of 0.077 cm2/(Vs). We emphasize that a simple synthetic approach, the introduction of end-capping groups which remove reactive functionalities, can be effective in the development of next-generation OFET and solar materials by promising better control of the polymer organization.
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U2 - 10.1021/acs.macromol.5b01252
DO - 10.1021/acs.macromol.5b01252
M3 - Article
AN - SCOPUS:84942247887
SN - 0024-9297
VL - 48
SP - 6369
EP - 6377
JO - Macromolecules
JF - Macromolecules
IS - 18
ER -