Abstract
The electronic structure of Tl2Mn2O7 was examined by performing tight binding band calculations. The overlap between the Mnt2g- and Tl 6s-block bands results in a partial filling of the Tl 6s-block bands. The associated Fermi surface consists of 12 cigar-shape electron pockets with each electron pocket about 1/1000 of the first Brillouin zone in size. The Tl 6s-block bands have orbital contributions from the Mn atoms, and the carrier density is very low. These are important for the occurrence of a colossal magnetoresistance in Tl2Mn2O7.
Original language | English (US) |
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Pages (from-to) | 417-421 |
Number of pages | 5 |
Journal | Solid State Communications |
Volume | 101 |
Issue number | 6 |
DOIs | |
State | Published - Feb 1997 |
Externally published | Yes |
ASJC Scopus subject areas
- Chemistry(all)
- Condensed Matter Physics
- Materials Chemistry