Electron transfer in molecules with conformational transitions

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Abstract

Intramolecular electron transfer reactions are considered with regard to conformational transitions in a molecule containing a donor and an acceptor. It is shown that the free energy of activation contains, besides the activation enthalpy, a temperature-dependent entropic term ΔS=a1+a2T.

Original languageEnglish (US)
Pages (from-to)131-136
Number of pages6
JournalChemical Physics Letters
Volume203
Issue number2-3
DOIs
Publication statusPublished - Feb 19 1993
Externally publishedYes

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

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