TY - JOUR
T1 - Electron tomography of nanoparticle clusters
T2 - Implications for atmospheric lifetimes and radiative forcing of soot
AU - van Poppel, Laura H.
AU - Friedrich, Heiner
AU - Spinsby, Jacob
AU - Chung, Serena H.
AU - Seinfeld, John H.
AU - Buseck, P R
PY - 2005/12/28
Y1 - 2005/12/28
N2 - Nanoparticles are ubiquitous in nature. Their large surface areas and consequent chemical reactivity typically result in their aggregation into clusters. Their chemical and physical properties depend on cluster shapes, which are commonly complex and unknown. This is the first application of electron tomography with a transmission electron microscope to quantitatively determine the three-dimensional (3D) shapes, volumes, and surface areas of nanoparticle clusters. We use soot (black carbon, BC) nanoparticles as an example because it is a major contributor to environmental degradation and global climate change. To the extent that our samples are representative, we find that quantitative measurements of soot surface areas and volumes derived from electron tomograms differ from geometrically derived values by, respectively, almost one and two orders of magnitude. Global sensitivity studies suggest that the global burden and direct radiative forcing of fractal BC are only about 60% of the value if it is assumed that BC has a spherical shape.
AB - Nanoparticles are ubiquitous in nature. Their large surface areas and consequent chemical reactivity typically result in their aggregation into clusters. Their chemical and physical properties depend on cluster shapes, which are commonly complex and unknown. This is the first application of electron tomography with a transmission electron microscope to quantitatively determine the three-dimensional (3D) shapes, volumes, and surface areas of nanoparticle clusters. We use soot (black carbon, BC) nanoparticles as an example because it is a major contributor to environmental degradation and global climate change. To the extent that our samples are representative, we find that quantitative measurements of soot surface areas and volumes derived from electron tomograms differ from geometrically derived values by, respectively, almost one and two orders of magnitude. Global sensitivity studies suggest that the global burden and direct radiative forcing of fractal BC are only about 60% of the value if it is assumed that BC has a spherical shape.
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U2 - 10.1029/2005GL024461
DO - 10.1029/2005GL024461
M3 - Article
AN - SCOPUS:32644451900
SN - 0094-8276
VL - 32
SP - 1
EP - 4
JO - Geophysical Research Letters
JF - Geophysical Research Letters
IS - 24
ER -