Electron correlation in doubly excited states of helium and extensions to beryllium and magnesium

Vladimiro Mujica, Osvaldo Goscinski, Erland Sangfelt

Research output: Contribution to journalArticle

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Abstract

Connections are established between the treatment of doubly excited states in He, using hyperspherical coordinates and the model of two particles on a sphere related to the use of dynamical group theory. The relevance of this for model wavefunctions of the type antisymmetrized geminal power (AGP) or separated pair approximation (SPA) is shown through the analysis and numerical applications of an effective equation for the valence geminal in Be and Mg.

Original languageEnglish (US)
Pages (from-to)473-484
Number of pages12
JournalChemical Physics
Volume87
Issue number3
DOIs
StatePublished - Jul 1 1984

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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