Electrical and optical characterization of Ag2V 4O11 and Ag4V2O6F 2

M. I. Bertoni, N. J. Kidner, T. O. Mason, T. A. Albrecht, E. M. Sorensen, K. R. Poeppelmeier

Research output: Contribution to journalArticle

18 Scopus citations

Abstract

The two silver vanadium oxide phases-Ag2V4O 11 and Ag4V2O6F2-were prepared by hydrothermal synthesis. The electrical conductivity of both silver vanadate powders was determined by the powder-solution-composite (PSC) method. The conductivities obtained were 0.0085∈±∈0.0005 and 0.0005∈±∈0.00015 S/cm for the Ag2V4O 11 and Ag4V2O6F2, respectively, the first such report for the Ag4V2O 6F2 phase. The optical gap and the transmission where studied by diffuse reflectance. Both were larger for Ag4V 2O6F2 than Ag2V4O 11, concomitant with a decrease in carrier content.

Original languageEnglish (US)
Pages (from-to)189-195
Number of pages7
JournalJournal of Electroceramics
Volume18
Issue number3-4
DOIs
StatePublished - Aug 1 2007
Externally publishedYes

Keywords

  • Conductivity
  • Hydrothermal synthesis
  • Silver vanadium oxide
  • Vanadium oxide fluoride

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Mechanics of Materials
  • Electrical and Electronic Engineering
  • Materials Chemistry

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    Bertoni, M. I., Kidner, N. J., Mason, T. O., Albrecht, T. A., Sorensen, E. M., & Poeppelmeier, K. R. (2007). Electrical and optical characterization of Ag2V 4O11 and Ag4V2O6F 2. Journal of Electroceramics, 18(3-4), 189-195. https://doi.org/10.1007/s10832-007-9025-6