TY - JOUR
T1 - Effect of P2O5 and FetO on the Viscosity and Slag Structure in Steelmaking Slags
AU - Wang, Z. J.
AU - Shu, Q. F.
AU - Sridhar, S.
AU - Zhang, M.
AU - Guo, M.
AU - Zhang, Z. T.
N1 - Funding Information:
Supports by the National High Technology Research and Development Program of China (863 Program, 2012AA06A114), the Key Projects in the National Science & Technology Pillar Program (2013BAC14B07), the Common Development Fund of Beijing, and the National Natural Science Foundation of China (51472007, 51272005, and 5172001) are acknowledged.
Publisher Copyright:
© 2015, The Minerals, Metals & Materials Society and ASM International.
PY - 2015/4/1
Y1 - 2015/4/1
N2 - The present paper investigates the influence of P2O5 and FetO on the viscosity and structure of steelmaking slags. An understanding of the viscous behavior and structure of FetO-bearing smelting slags is essential to control the dephosphorization in steelmaking process and to efficiently recycle the phosphorus from steelmaking slags. It is found that the viscosity of CaO-SiO2-Al2O3-MgO-FetO-P2O5 slags slightly increases with increasing P2O5 content, while the viscosity decreases with increasing FetO content. The degree of the polymerization of quenched slags, determined from Raman spectra, is found to increase with increasing P2O5 content and decrease with increasing FetO content. It is also noted that the peaks of Raman spectra between 800 and 1200 cm−1 were nearly absent at the FetO content of 22.46 wt pct; whereas according to 29Si MAS-NMR and FTIR analysis, it is clearly seen that the [SiO4]-tetrahedra-related peaks existed even for the same slag. This may confirm that small quantities of extra-framework iron species can absorb the Raman scattering and damp the Raman signal intensity and the presence of FetO in the slag does not necessarily eliminate [SiO4]-tetrahedra.
AB - The present paper investigates the influence of P2O5 and FetO on the viscosity and structure of steelmaking slags. An understanding of the viscous behavior and structure of FetO-bearing smelting slags is essential to control the dephosphorization in steelmaking process and to efficiently recycle the phosphorus from steelmaking slags. It is found that the viscosity of CaO-SiO2-Al2O3-MgO-FetO-P2O5 slags slightly increases with increasing P2O5 content, while the viscosity decreases with increasing FetO content. The degree of the polymerization of quenched slags, determined from Raman spectra, is found to increase with increasing P2O5 content and decrease with increasing FetO content. It is also noted that the peaks of Raman spectra between 800 and 1200 cm−1 were nearly absent at the FetO content of 22.46 wt pct; whereas according to 29Si MAS-NMR and FTIR analysis, it is clearly seen that the [SiO4]-tetrahedra-related peaks existed even for the same slag. This may confirm that small quantities of extra-framework iron species can absorb the Raman scattering and damp the Raman signal intensity and the presence of FetO in the slag does not necessarily eliminate [SiO4]-tetrahedra.
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U2 - 10.1007/s11663-014-0270-1
DO - 10.1007/s11663-014-0270-1
M3 - Article
AN - SCOPUS:84939989839
VL - 46
SP - 758
EP - 765
JO - Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
JF - Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science
SN - 1073-5615
IS - 2
ER -