Effect of pressure on conductivity in liquid and glassy states of a superionic conducting glass

Charles Angell, Jinfeng Zhou

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

To observe whether pressure acting on the liquid state of a fast ion conducting vitreous solid electrolyte has a very different effect from pressure acting on the fixed structure vitreous state, measurements have been performed on (AgI)40(AgPO3)60 over a range of pressures and temperatures. Below Tg, conductivity decreases according to classic transition state theory expressions with volume of activation close to the mobile ion volume. Pressure applied near and above Tg has only a slightly different effect than the same pressure applied well below Tg below, in contrast to the pressure effect on viscosity above Tg. An explanation links weak pressure effects to previously known weak quenching (fictive temperature) effects, through the high decoupling index.

Original languageEnglish (US)
Pages (from-to)243-245
Number of pages3
JournalSolid State Ionics
Volume34
Issue number4
DOIs
StatePublished - 1989
Externally publishedYes

Fingerprint

conduction
Glass
conductivity
glass
Liquids
liquids
Pressure effects
pressure effects
Ions
Solid electrolytes
solid electrolytes
decoupling
Thermal effects
temperature effects
Quenching
ions
Chemical activation
quenching
activation
Viscosity

ASJC Scopus subject areas

  • Electrochemistry
  • Physical and Theoretical Chemistry
  • Energy Engineering and Power Technology
  • Materials Chemistry
  • Condensed Matter Physics

Cite this

Effect of pressure on conductivity in liquid and glassy states of a superionic conducting glass. / Angell, Charles; Zhou, Jinfeng.

In: Solid State Ionics, Vol. 34, No. 4, 1989, p. 243-245.

Research output: Contribution to journalArticle

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