Effect of N-substituents on protonation chemistry of trichlorophosphazenes

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Abstract

The protonation chemistry of trichlorophosphazene (R1-N=PCl3) with sulfonic acids (R2SO3H) was found to be affected by the N-substituents R1, yielding bis(sulfonyl)imides containing both R1 and R2, and mixed sulfonylphosphonyl imides containing either R1 or R2. In the formation of the latter a hitherto unobserved chemistry occurred. An intramolecular 'imine SN2' mechanism was proposed to rationalize the reactions observed. (C) 2000 Elsevier Science S.A.

Original languageEnglish (US)
Pages (from-to)16-23
Number of pages8
JournalInorganica Chimica Acta
Volume298
Issue number1
DOIs
StatePublished - Jan 30 2000

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Keywords

  • Bis(sulfonyl)imides
  • Protonation chemistry
  • Trichlorophosphazenes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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