Effect of microstructure of MFI-type zeolite membranes on separation of xylene isomers

J. L. O'Brien-Abraham, M. Kanezashi, Jerry Lin

Research output: Chapter in Book/Report/Conference proceedingChapter

1 Scopus citations

Abstract

Effective separation of xylene isomers is possible with pervaporation through MFI-silicalite membranes. The effect of microstructural differences in silicalite membranes on the separation of xylene isomers was investigated. MFI-type zeolite membranes with random and ordered orientations were synthesized using a seeded growth method with and without organic templates. It was found that template-free random oriented membranes were capable of pure component p/o xylene separation factors of about 20 and p-xylene flux of 0.3 kg m-2 hr-1 . The membranes with preferred orientation showed comparable flux of xylene isomers but decreased selectivities ranging from 2 to 3. These results indicate that microstructure strongly affects the ability of the membrane to perform xylene separation.

Original languageEnglish (US)
Title of host publicationFrom Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference
PublisherElsevier Inc.
Pages967-974
Number of pages8
EditionA
ISBN (Print)0444530681, 9780444530684
DOIs
StatePublished - Jan 1 2007

Publication series

NameStudies in Surface Science and Catalysis
NumberA
Volume170
ISSN (Print)0167-2991

ASJC Scopus subject areas

  • Catalysis
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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    O'Brien-Abraham, J. L., Kanezashi, M., & Lin, J. (2007). Effect of microstructure of MFI-type zeolite membranes on separation of xylene isomers. In From Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference (A ed., pp. 967-974). (Studies in Surface Science and Catalysis; Vol. 170, No. A). Elsevier Inc.. https://doi.org/10.1016/S0167-2991(07)80947-5