TY - JOUR
T1 - Effect of hydrogen bonds on the thermodynamic behavior of liquid water
AU - Poole, Peter H.
AU - Sciortino, Francesco
AU - Grande, Tor
AU - Stanley, H. Eugene
AU - Angell, Charles
PY - 1994
Y1 - 1994
N2 - We propose an extension of the van der Waals equation which is designed to incorporate, in an approximate fashion, the effects of the network of hydrogen bonds that exist in liquid water. The resulting model qualitatively predicts the unique thermodynamic properties of water, including those of the deeply supercooled states. It also reconciles two proposals for the phase behavior of supercooled and stretched water and provides a thermodynamic origin for the observed polymorphism of the amorphous solid form of water.
AB - We propose an extension of the van der Waals equation which is designed to incorporate, in an approximate fashion, the effects of the network of hydrogen bonds that exist in liquid water. The resulting model qualitatively predicts the unique thermodynamic properties of water, including those of the deeply supercooled states. It also reconciles two proposals for the phase behavior of supercooled and stretched water and provides a thermodynamic origin for the observed polymorphism of the amorphous solid form of water.
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U2 - 10.1103/PhysRevLett.73.1632
DO - 10.1103/PhysRevLett.73.1632
M3 - Article
AN - SCOPUS:0000965995
SN - 0031-9007
VL - 73
SP - 1632
EP - 1635
JO - Physical Review Letters
JF - Physical Review Letters
IS - 12
ER -