Dy- and Tb-doped CeO2-Ni cermets for solid oxide fuel cell anodes: electrochemical fabrication, structural characterization, and electrocatalytic performance

Massimo Catalano, Antonietta Taurino, Jiangtao Zhu, Peter Crozier, Simone Dal Zilio, Matteo Amati, Luca Gregoratti, Benedetto Bozzini, Claudio Mele

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Dy- and Tb-doped CeO2-Ni cermets for highly active solid-oxide fuel-cell (SOFC) anodes were fabricated by a one-pot electrodeposition process. Undoped, singly-doped, and co-doped powders were synthesized in an X-ray amorphous state, heat treated in air, and characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM) at different crystallization stages. In particular, in situ TEM analyses were carried out during heating in an oxygen atmosphere, in order to follow the evolution of structure and morphology and to understand the role of the dopants. The key structural effect of dopants was the inhibition of grain coarsening during heat treatment. Functional tests were carried out with micro-single chamber SOFCs, fed with a CH4/O2 mixture, the anodes of which were prepared with the CeO2-Ni powders synthesized in this study. A correlation was established between the electrocatalytic performance and the morphology of the anodic material, pinpointing that the finer and more homogeneous nanocrystalline structure of the doped powders results in better-defined and more active catalytic sites, thus improving the performance of the cell. [Figure not available: see fulltext.].

Original languageEnglish (US)
Pages (from-to)3761-3773
Number of pages13
JournalJournal of Solid State Electrochemistry
Volume22
Issue number12
DOIs
StatePublished - Dec 1 2018

Keywords

  • CeO-Ni cermet
  • Dy and Tb doping
  • Electrodeposition
  • In situ TEM
  • Solid-oxide fuel-cell

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Electrochemistry
  • Electrical and Electronic Engineering

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