Doped diamond thin film electron sources for thermionic energy conversion

Franz A M Koeck, Robert Nemanich, Jeff Sharp

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Thermionic energy conversion is a process that allows direct conversion of heat into electrical energy without mechanically moving components. In a thermionic converter electrons from the emitter traverse a small gap, are collected by a counter-electrode, the collector, and a self generated voltage develops across the gap. We have prepared prepared an ultra-nanocrystalline diamond (UNCD) based thermionic electron emitter that exhibits a low effective work function of typically 1.4 eV. This was attributed in part to reduced band bending and to the negative electron affinity (NEA) surface. A thermionic energy converter comprised of 2 diamond electrodes were positioned to establish a 25 micron gap and the emitter which was operated at temperatures up to 700 Celsius with a self generated open circuit voltage of 0.35 V. The reduced power output of the device was in part attributed to space charge effects and diamond film resistivity. Utilizing surface ionization effects at the emitter by introducing atomic hydrogen into the converter gap resulted in significant power output increase. With atomic hydrogen in the gap, the converter was operated up to 750 Celsius indicative of efficient surface ionization for charge transfer as well as a stable NEA diamond surface.

Original languageEnglish (US)
Title of host publication2013 26th International Vacuum Nanoelectronics Conference, IVNC 2013
DOIs
StatePublished - 2013
Event2013 26th International Vacuum Nanoelectronics Conference, IVNC 2013 - Roanoke, VA, United States
Duration: Jul 8 2013Jul 12 2013

Other

Other2013 26th International Vacuum Nanoelectronics Conference, IVNC 2013
CountryUnited States
CityRoanoke, VA
Period7/8/137/12/13

Fingerprint

Electron sources
Diamond films
Energy conversion
Thin films
Diamonds
Electron affinity
Ionization
Hydrogen
Electrodes
Electrons
Open circuit voltage
Electric space charge
Charge transfer
Electric potential
Temperature

Keywords

  • chemical vapor deposition
  • Diamond
  • doping
  • energy conversion
  • thermionic electron emission

ASJC Scopus subject areas

  • Electrical and Electronic Engineering

Cite this

Koeck, F. A. M., Nemanich, R., & Sharp, J. (2013). Doped diamond thin film electron sources for thermionic energy conversion. In 2013 26th International Vacuum Nanoelectronics Conference, IVNC 2013 [6624727] https://doi.org/10.1109/IVNC.2013.6624727

Doped diamond thin film electron sources for thermionic energy conversion. / Koeck, Franz A M; Nemanich, Robert; Sharp, Jeff.

2013 26th International Vacuum Nanoelectronics Conference, IVNC 2013. 2013. 6624727.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Koeck, FAM, Nemanich, R & Sharp, J 2013, Doped diamond thin film electron sources for thermionic energy conversion. in 2013 26th International Vacuum Nanoelectronics Conference, IVNC 2013., 6624727, 2013 26th International Vacuum Nanoelectronics Conference, IVNC 2013, Roanoke, VA, United States, 7/8/13. https://doi.org/10.1109/IVNC.2013.6624727
Koeck FAM, Nemanich R, Sharp J. Doped diamond thin film electron sources for thermionic energy conversion. In 2013 26th International Vacuum Nanoelectronics Conference, IVNC 2013. 2013. 6624727 https://doi.org/10.1109/IVNC.2013.6624727
Koeck, Franz A M ; Nemanich, Robert ; Sharp, Jeff. / Doped diamond thin film electron sources for thermionic energy conversion. 2013 26th International Vacuum Nanoelectronics Conference, IVNC 2013. 2013.
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