Direct imaging of zirconia pillars in montmorillonite by analytical electron microscopy

Peter Crozier, M. Pan, C. Bateman, J. J. Alcaraz, J. S. Holmgren

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Analytical electron microscopy was used to confirm the location of pillars of zirconia in pillared montmorillonite. Data show that the pillared clay is of "high" quality, with surface areas ranging from 200 to 250 m2/g and (001) spacings in the 17-18 Å range. The zirconia-rich pillars were observed using bright-field imaging, annular dark-field imaging, and energy-filtered imaging. The composition of the pillars was confirmed by performing nano-analysis using energy-dispersive X-ray spectroscopy and electron energy-loss spectroscopy. The pillars apparently have an irregular shape <50 Å in size. The shape and relatively large size of the pillars suggest that zirconia dispersion is not ideally distributed in this sample. This study is apparently the first report of electron microscopy observation of pillaring material in clays.

Original languageEnglish (US)
Pages (from-to)683-687
Number of pages5
JournalClays and Clay Minerals
Volume47
Issue number6
StatePublished - 1999

Fingerprint

Bentonite
montmorillonite
pillar
electron microscopy
Electron microscopy
image analysis
Imaging techniques
spectroscopy
clay
energy-dispersive X-ray analysis
Electron energy loss spectroscopy
energy
pillared clay
surface area
electrons
spatial distribution
X-ray spectroscopy
Chemical analysis
spacing
zirconium oxide

Keywords

  • Clays
  • Electron Energy-Loss Spectroscopy
  • Elemental Mapping
  • Energy-Filtered Imaging
  • Image Analysis
  • Materials Characterization

ASJC Scopus subject areas

  • Soil Science
  • Earth and Planetary Sciences (miscellaneous)
  • Geochemistry and Petrology
  • Water Science and Technology

Cite this

Crozier, P., Pan, M., Bateman, C., Alcaraz, J. J., & Holmgren, J. S. (1999). Direct imaging of zirconia pillars in montmorillonite by analytical electron microscopy. Clays and Clay Minerals, 47(6), 683-687.

Direct imaging of zirconia pillars in montmorillonite by analytical electron microscopy. / Crozier, Peter; Pan, M.; Bateman, C.; Alcaraz, J. J.; Holmgren, J. S.

In: Clays and Clay Minerals, Vol. 47, No. 6, 1999, p. 683-687.

Research output: Contribution to journalArticle

Crozier, P, Pan, M, Bateman, C, Alcaraz, JJ & Holmgren, JS 1999, 'Direct imaging of zirconia pillars in montmorillonite by analytical electron microscopy', Clays and Clay Minerals, vol. 47, no. 6, pp. 683-687.
Crozier, Peter ; Pan, M. ; Bateman, C. ; Alcaraz, J. J. ; Holmgren, J. S. / Direct imaging of zirconia pillars in montmorillonite by analytical electron microscopy. In: Clays and Clay Minerals. 1999 ; Vol. 47, No. 6. pp. 683-687.
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