Direct determination of kinetic fragility indices of glassforming liquids by differential scanning calorimetry: Kinetic versus thermodynamic fragilities

Li Min Wang; V. Velikov; Charles Angell

doi:10.1063/1.1517607

Direct determination of kinetic fragility indices of glassforming liquids by differential scanning calorimetry: Kinetic versus thermodynamic fragilities

Li Min Wang, V. Velikov, Charles Angell

Molecular Sciences, School of (SMS)

Research output: Contribution to journal › Article › peer-review

229 Scopus citations

Abstract

By using differential scanning calorimetry, kinetic and thermodynamic measures of the glassformer property "fragility" were made for a glassformer that permits both glass transition and fusion to be observed. For a series of glassformers covering the F_1/2 range from 0.5 up to 0.8, the thermodynamic and kinetic measures of fragility were again found to be similar.

Original language	English (US)
Pages (from-to)	10184-10192
Number of pages	9
Journal	Journal of Chemical Physics
Volume	117
Issue number	22
DOIs	https://doi.org/10.1063/1.1517607
State	Published - Dec 8 2002

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Access to Document

10.1063/1.1517607

Cite this

@article{517c288acca74e479d3eddff7f875bc9,

title = "Direct determination of kinetic fragility indices of glassforming liquids by differential scanning calorimetry: Kinetic versus thermodynamic fragilities",

abstract = "By using differential scanning calorimetry, kinetic and thermodynamic measures of the glassformer property {"}fragility{"} were made for a glassformer that permits both glass transition and fusion to be observed. For a series of glassformers covering the F1/2 range from 0.5 up to 0.8, the thermodynamic and kinetic measures of fragility were again found to be similar.",

author = "Wang, {Li Min} and V. Velikov and Charles Angell",

year = "2002",

month = dec,

day = "8",

doi = "10.1063/1.1517607",

language = "English (US)",

volume = "117",

pages = "10184--10192",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

number = "22",

}

TY - JOUR

T1 - Direct determination of kinetic fragility indices of glassforming liquids by differential scanning calorimetry

T2 - Kinetic versus thermodynamic fragilities

AU - Wang, Li Min

AU - Velikov, V.

AU - Angell, Charles

PY - 2002/12/8

Y1 - 2002/12/8

N2 - By using differential scanning calorimetry, kinetic and thermodynamic measures of the glassformer property "fragility" were made for a glassformer that permits both glass transition and fusion to be observed. For a series of glassformers covering the F1/2 range from 0.5 up to 0.8, the thermodynamic and kinetic measures of fragility were again found to be similar.

AB - By using differential scanning calorimetry, kinetic and thermodynamic measures of the glassformer property "fragility" were made for a glassformer that permits both glass transition and fusion to be observed. For a series of glassformers covering the F1/2 range from 0.5 up to 0.8, the thermodynamic and kinetic measures of fragility were again found to be similar.

UR - http://www.scopus.com/inward/record.url?scp=0037045179&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037045179&partnerID=8YFLogxK

U2 - 10.1063/1.1517607

DO - 10.1063/1.1517607

M3 - Article

AN - SCOPUS:0037045179

SN - 0021-9606

VL - 117

SP - 10184

EP - 10192

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 22

ER -

Direct determination of kinetic fragility indices of glassforming liquids by differential scanning calorimetry: Kinetic versus thermodynamic fragilities

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this