Determination of the electric dipole moment and excited state Fermi contact parameter of the GeCH radical

Tony C. Smith, Dennis J. Clouthier, Timothy Steimle

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Laser-induced fluorescence spectroscopy was used to determine the electric dipole moments and excited state Fermi contact parameter of GeCH radical. The spectral linewidth was reduced to 35 MHz using well-collimated molecular beam of radicals. A single upper state Fermi contact parameter was varied to model the observed hyperfine splittings of the 12 rotational lines. It was observed that larger GeCH values suggested substantial spin polarization contribution with higher density of electron states.

Original languageEnglish (US)
Pages (from-to)5047-5052
Number of pages6
JournalJournal of Chemical Physics
Volume115
Issue number11
DOIs
StatePublished - Sep 15 2001

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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