Design for optimized electromechanical transduction in ionic polymer transducers fabricated with architecturally controlled ionomers

Andrew J. Duncan, Timothy E. Long, Donald J. Leo

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Ionic polymer transducers (IPT) are devices composed of ionomeric membranes, high surface area electrodes, and ion-conducting electrolytes that are capable of electromechanical transduction. This study aims to optimize the interactions between all three of these components to design a high performance IPT with novel ionomers. Equivalent circuit modeling of impedance data allowed for estimations of IPT capacitance due to changes in the compositions of the electrodes. Various methods for control of electrolyte uptake resulted in a range of ionic conductivity when combined with novel ionomers that vary in polymer backbone architecture and charge content. Although the ionic liquid was found to dominate the magnitude of the conductivity, the pathway for uptake was significant in determination of the overall maximum values. Combination of these optimized parameters for capacitance and ionic conductivity identified design criteria for potentially high performance IPTs to investigate the benefits of these novel ionomers in electroactive devices.

Original languageEnglish (US)
Title of host publicationProceedings of the ASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems 2009, SMASIS2009
Pages105-113
Number of pages9
DOIs
StatePublished - 2009
Externally publishedYes
Event2009 ASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS2009 - Oxnard, CA, United States
Duration: Sep 21 2009Sep 23 2009

Publication series

NameProceedings of the ASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems 2009, SMASIS2009
Volume2

Other

Other2009 ASME Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS2009
CountryUnited States
CityOxnard, CA
Period9/21/099/23/09

ASJC Scopus subject areas

  • Computational Mechanics
  • Mechanics of Materials

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